物理化学学报 >> 2002, Vol. 18 >> Issue (03): 268-271.doi: 10.3866/PKU.WHXB20020316

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镍纳米线电极对乙醇的电催化氧化动力学参数的测定

孔景临;薛宽宏;邵颖;何春建;陈巧玲   

  1. 南京师范大学化学系，南京　210097
  • 收稿日期:2001-07-23 修回日期:2001-10-29 发布日期:2002-03-15
  • 通讯作者: 薛宽宏 E-mail:khxue@njnu.edu.cn

Measurements for the Kinetic Parameters of Electrocatalytic Oxidation of Ethanol at the Nickel Nanowire Electrode

Kong Jing-Lin;Xue Kuan-Hong;Shao Ying;He Chun-Jian;Chen Qiao-Ling   

  1. Department of Chemistry, Nanjing Normal University, Nanjing　210097
  • Received:2001-07-23 Revised:2001-10-29 Published:2002-03-15
  • Contact: Xue Kuan-Hong E-mail:khxue@njnu.edu.cn

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摘要： 循环伏安实验表明,以多孔氧化铝膜为模板制备出的镍纳米线电极对乙醇的电化学催化氧化具有很高的催化活性.用强制对流流体动力学的方法求算出乙醇在镍纳米线电极上的电子传递过程的速率常数高于许多文献报导值,而电子传递过程的随后步骤的速率常数相近.

关键词: 镍纳米线, 电催化, 乙醇, 循环伏安, 强制对流流体动力学

Abstract: The electrocatalyticoxidation of ethanol at the nickel nanowire electrode was investigated by cyclic voltammetry and the forced convection hydrodynamic method. The kinetic parameters of the reaction were measured and it was found that the rate constants of the electron transfer processes on the nanowire electrode were much higher than those reported in the literatures, but the rate constant of the step following the electron transfer process was comparable to the reported values.

Key words: Nickel nanowire, Electrocatalysis, Ethanol, Cyclic voltammetry, Forced convection hydrodynamic method