物理化学学报 >> 2001, Vol. 17 >> Issue (08): 718-722.doi: 10.3866/PKU.WHXB20010810

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单壁碳纳米管的CVD合成及管径分布

魏忠;陈言;刘忠范   

  1. 北京大学化学与分子工程学院 纳米科学技术研究中心，北京　100871
  • 收稿日期:2001-02-27 修回日期:2001-04-05 发布日期:2001-08-15
  • 通讯作者: 刘忠范 E-mail:lzf@chem.pku.edu.cn

CVD Synthesis and Diameter Distribution of SingleWalled Carbon Nanotubes

Wei Zhong;Chen Yan;Liu Zhong-Fan   

  1. Center of Nanoscale Science and Technology, College of Chemistry ＆Molecular Engineering, Peking University,Beijing　100871
  • Received:2001-02-27 Revised:2001-04-05 Published:2001-08-15
  • Contact: Liu Zhong-Fan E-mail:lzf@chem.pku.edu.cn

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摘要： 甲烷在以活性氧化铝为载体的Fe、Co、Ni、Ru等催化剂上于850 ℃分解并生成直径为0.8～5 nm的单壁碳纳米管.预先将催化剂在1100 ℃焙烧，能够减少产物中无定形碳的生成.拉曼光谱结果表明，由该法制备的碳纳米管的管径分布主要受温度的影响，较低温度有利于较小直径的单壁碳纳米管的生成和较好的管径选择性.

关键词: 单壁碳纳米管, 化学气相沉积（CVD）, Raman光谱, 管径分布

Abstract: Singlewalled carbon nanotubes (SWNTs) were synthesized by the decomposition of methane on Al2O3 supported Fe,Co,Ni,Ru catalysts at 850 ℃. The diameters of the single walled carbon nanotubes were in the range of 0.8～5 nm. The amorphous carbon impurity could be reduced by pretreatment of catalysts at 1100 ℃. Raman spectra showed that the diameter distributions of the SWNTs were mainly influenced by the reaction temperature. At lower temperature small diameter nanotubes were favored and better selectivity of diameter could be achieved.

Key words: Single-walled carbon nanotubes, CVD, Raman spectroscopy, Diameter distribution