物理化学学报 >> 2000, Vol. 16 >> Issue (12): 1057-1061.doi: 10.3866/PKU.WHXB20001201

通讯    下一篇

高效率变色WO3多聚体/1,10-DAD自组装薄膜的制备

陈朝晖, 马颖, 姚建年   

  1. 中国科学院化学研究所分子科学中心 北京 100080
  • 收稿日期:2000-08-25 修回日期:2000-09-25 发布日期:2000-12-15
  • 通讯作者: 姚建年 E-mail:jnyao@ipc.ac.cn

High-Efficlent Photochromic WO3-polymer/1,10-DAD Self-assembly Films Modified by Organic Molecules

Chen Zhao-Hui, Ma Ying, Yao Jian-Nian   

  1. Center for Molecular Science,Institute of Chemistry,Chinese Acadomy of Sciences,Beijing 100080
  • Received:2000-08-25 Revised:2000-09-25 Published:2000-12-15
  • Contact: Yao Jian-Nian E-mail:jnyao@ipc.ac.cn

关键词: 分子沉积膜, 自组装, 光致变色, WO3

Abstract:

A novel high-efficient photochromic self-assembly multilayered film has been fabricated from WO3 and 1,10-DAD solution using molecular deposition technique.The dependence of photochromic behavior on with WO3 in the WO3-polymer/1,10-DAD self-assembly film was discussed in comparison with WO3/4,4-BAMBp system.The results clearly show that organic molecules determine the charge density of the photo-induced charge-tracsfer complexes,andthus manipu-late the structure and the photochromic properties of the films.

Key words: Molecular deposition films, Self-assembly, Photochromism, WO3