物理化学学报 >> 1999, Vol. 15 >> Issue (07): 647-651.doi: 10.3866/PKU.WHXB19990713

研究简报 上一篇    下一篇

加氢脱硫催化剂各组分的相互作用与催化性能

程伟, 张继炎, 王日杰, 王亚权, 何菲, 周俐   

  1. 天津大学化工学院，碳一化工国家重点实验室，天津 300072|长岭炼油化工总厂研究院，岳阳 414012
  • 收稿日期:1998-09-04 修回日期:1998-11-16 发布日期:1999-07-15
  • 通讯作者: 程伟

Properties of Hydrodesulfurization Catalysts and Interaection among their Ingredients

Cheng Wei, Zhang Ji-Yan, Wang Ri-Jie, Wang Ya-Quan, He Fei, Zhou Li   

  1. College of Chemical Engineering,Tianjin University;State Key Laboratory of Chemical Technolegy Tianjin 300072|Research Institute of Changlian General Refining Chemical Works,Yueyang Hunan 414012
  • Received:1998-09-04 Revised:1998-11-16 Published:1999-07-15
  • Contact: Cheng Wei

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关键词: 加氢脱硫催化, X射线衍射, 程序升温还原, X光电子能谱, 协同效应

Abstract:

The effects of the synergism among NiO, MoO3 and Al2O3 on the properties of the hydrodesulfurization (HDS) catalysts have been investigated by means of the techniques of XRD, TPR,XPS and chemisorption. The results indicate that the dispersion of MoO3 on the catalyst is improved owing to the presence of NiO. A complex on the surface of the support, formed by the action of NiO with MoO3 can be easily reduced and sulphized. There is also synergism on catalysts Co-Mo/Al2O3 and Ni-W/Al2O3, but they differ from the one on Ni-Mo/Al2O3 in some aspects.

Key words: Hydrodesulfurization(HDS) catalysts, XRD, TPR, XPS, Synergism effect