物理化学学报 >> 2001, Vol. 17 >> Issue (03): 234-237.doi: 10.3866/PKU.WHXB20010309

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手性苏氨酸卟啉锌配合物的圆二色谱

彭小彬;梁世强   

  1. 华南理工大学应用化学系，广州　510641;仲凯农业技术学院基础部，广州　510225
  • 收稿日期:2000-07-31 修回日期:2000-10-08 发布日期:2001-03-15
  • 通讯作者: 彭小彬 E-mail:chxbpeng@scut.edu.cn

CD Spectrum of Chiral Threonine Modified Porphyrinatozinc (II)

Peng Xiao-Bin;Liang Shi-Qiang   

  1. Department of Applied Chemistry, South China University of Technology,Guangzhou 　510641;Zhongkai College of Agricultural Technology, Guangzhou　510225
  • Received:2000-07-31 Revised:2000-10-08 Published:2001-03-15
  • Contact: Peng Xiao-Bin E-mail:chxbpeng@scut.edu.cn

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关键词: 手性氨基酸, 锌卟啉配合物, CD光谱

Abstract: The synthesized chiral amino acid modified porphyrinatozinc(II) exhibi ted characterized CD spectrum in Soret region. The coupling between the carbonyl group of the amino acid residue and the porphyrin unit is the origin of the CD spectrum. The premise of the above coupling is the intramolecular interaction be tween the amino acid residue and the porphyrin unit.

Key words: Chiral amino acid, Porphyrinatozinc(II), CD spectrum