物理化学学报 >> 1993, Vol. 9 >> Issue (03): 319-324.doi: 10.3866/PKU.WHXB19930308

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固体聚合物电解质在肉桂醇电解氧化中的应用(II)——后续化学反应在电催化反应中的地位及其影响因素

陈震   

  1. 福建师范大学实验中心，福州市 350007
  • 收稿日期:1991-11-18 修回日期:1992-04-08 发布日期:1993-06-15
  • 通讯作者: 陈震

Application of Solid Polymer Electrolyte in Electrooxidation of Cinnamyl Alcohol(II)——Influence of Follow-up Reaction on Electro-catalytic Reaction

Chen Zhen   

  1. Center of experiment, Fujian Normal University, Fuzhou 350007
  • Received:1991-11-18 Revised:1992-04-08 Published:1993-06-15
  • Contact: Chen Zhen

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摘要： 对影响肉桂醇电极氧化的各种因素作了进一步的讨论. 实验结果表明固体聚合物电解质内水的含量、pH 以及浸入离子交换膜中的二价锰离子的浓度均对该电极反应的电位以及后续化学反应的速度有很大的影响, 在较高的温度下反应时, 有利手提高生成肉桂醛的电流效率.

关键词: SPE技术, 阳离子交换膜, 固体聚合物电解质, 肉桂醇

Abstract: The electrochemical oxidation of cinnamyl alcohol proceeds via consecutive reaction, the follow-up reaction is important in the mediatory systems. The reaction rate de-creased with an increase in water content. An increase in acid concentration also accelares the reaction rate. As expected, the increase of reaction temperature shows an enhancement of the reaction rate for aldehyde and acid formation simultaneously.

Key words: SPE(Solid Polymer Electrolyte) technology, Cation exchange membrane, Solid polymer electrolyte, Cinnamyl alcohol