物理化学学报 >> 1992, Vol. 8 >> Issue (03): 358-363.doi: 10.3866/PKU.WHXB19920314

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红外光谱定量法研究醇在正烷烃中的氢键缔合

许建和; 孙贤达; 卢为琴; 高鸿锦   

  1. 清华大学化学系，北京 100084
  • 收稿日期:1991-02-09 修回日期:1991-07-30 发布日期:1992-06-15
  • 通讯作者: 高鸿锦

Study of Hydrogen Bond Association of Alcohol Molecules in Alkanes by IR Quantitative Analysis

Xu Jian-He; Sun Xian-Da; Lu Wei-Qin; Gao Hong-Jin   

  1. Department of Chemistry, Tsinghua University, Beijing 100084
  • Received:1991-02-09 Revised:1991-07-30 Published:1992-06-15
  • Contact: Gao Hong-Jin

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摘要： 测定了正十六醇-正己烷烃溶液(0.01～0.20 mol·L~(-1))在不同浓度下的红外光谱, 并用付里叶自去卷积-曲线拟合法(Fourier Self-decon-volution and curve-fitting)对谱图进行了解析。结果将醇羟基峰归属为: (1)单体羟基峰(3646.6 m~(-1))、(2)链状缔合体末端游离羟基峰(3633.8 cm~(-1))、(3)环状二聚体羟基峰(3535.1 cm~(-1))、(4)链式二聚体缔合羟基峰(3474c m~(-1))和(5)链状多聚体组合羟基峰(3337 cm~(-1))五种类型, 并得出它们随浓度的分布规律。

关键词: 红外光谱定量法, 醇-烷体系, 氢键缔合

Abstract: The IR spectra of n-C_(16)H_(33)OH/n-C_6H_(14)(n-hexadecanol/n-hexane) system in seven different alcohol concentrations (0.01-0.20 mol·L~(-1)) were measured and analysed by combined Fourier self-deconyolution and curve-fitting methods. The types of associa-tion in the system can be identified and their distribution can be evaluated.

Key words: IR quantitative analysis, Alcohol/Alkane system, Hydrogen bond association