物理化学学报 >> 1995, Vol. 11 >> Issue (11): 961-964.doi: 10.3866/PKU.WHXB19951101

通讯    下一篇

CH3N3的光解—生成三线态CH3N自由基的光谱证据

应文明, 夏煜, 尚海蓉, 赵新生, 唐有祺   

  1. 北京大学化学系及物理化学研究所,北京 100871
  • 收稿日期:1995-08-08 修回日期:1995-08-28 发布日期:1995-11-15
  • 通讯作者: 赵新生

Photodissociation of CH3N3—Spectral Evidences for the Formation of Triplet CH3N Radical

Ying Wen-Ming, Xia Yu, Shang Hai-Rong, Zhao Xin-Sheng, Tang You-Qi   

  1. Department of Chemistry,and Institute of Physical Chemistry,Peking University,Beijing 100871
  • Received:1995-08-08 Revised:1995-08-28 Published:1995-11-15
  • Contact: Zhao Xin-Sheng

摘要:

研究了CH3N3在第一电子吸收带的光解,获得了生成三线态CH3N自由基的重要证据并对可能的反应机制进行了讨论.其机理以激发态CH3N3经单线态三线态相互作用后解离生成三线态自由基的可能性较大.

关键词: 光解, 自由基, 发射谱, 荧光

Key words: Photodissociation, Radical, Emission spectrum, Fluorescence