物理化学学报 >> 1996, Vol. 12 >> Issue (01): 18-21.doi: 10.3866/PKU.WHXB19960105

研究论文 上一篇    下一篇

光解苯半醌和2-羟基-2-丙基自由基的CIDEP谱

张文敏,何光龙,陆同兴   

  1. 安徽师范大学化学系，物理系，芜湖 241000
  • 收稿日期:1995-03-07 修回日期:1995-05-10 发布日期:1996-01-15
  • 通讯作者: 张文敏

The CIDEP Spectra of Photolized p-benzosemiquinone and 2-hydroxy-2-propyl Radicals

Zhang Wen-Min,He Guang-Long,Lu Tong-Xing   

  1. Department of Chemistry,Department of Physics,Anhui Normal University,Wuhu 241000
  • Received:1995-03-07 Revised:1995-05-10 Published:1996-01-15
  • Contact: Zhang Wen-Min

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摘要：

用高时间分辨ESR波谱仪测量了光解苯半醌和2－羟基－2－丙基自由基的CIDEP谱，苯半醌自由基的CIDEP属TM机理．实验研究了微波功率、溶液浓度对苯半醌自由基的CIDEP谱时间演化的影响．2－羟基－2－丙基自由基的CIDEP属RPM机理，实验研究了自旋极化的生成环境．

关键词: 化学诱导动态电子极化, 时间分辨电子自旋共振, 光解苯半醌自由基, 光解2-羟基-2-丙基自由基

Abstract:

 The CIDEP of photolized р-benzosemiquinone and 2-hydroxy-2-propyl radicals was measured with time-resolved ESR spectrometer. The CIDEP of р-benzosemiquinone radical is belong to TM mechanism. The influence of microwave power and solution concentration on evoluation was investigated. The condition of spin polarization of 2 hydroxy-2-propyl radical, which is belong to RPM mechanism, was investigated.

Key words: CIDEP;Time-resolved ESR, Photolized p-benzosemiquinone radical, Photolized 2-hydroxy-2-propyl radical