物理化学学报 >> 2003, Vol. 19 >> Issue (02): 171-173.doi: 10.3866/PKU.WHXB20030217

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TiO2/聚丙烯酸丁酯纳米复合薄膜的制备及结构表征

张晟卯;张治军;党鸿辛;刘维民;薛群基   

  1. 中国科学院兰州化学物理研究所, 固体润滑国家重点实验室,兰州　730000; 河南大学润滑与功能材料重点实验室,开封　475001
  • 收稿日期:2002-05-23 修回日期:2002-08-05 发布日期:2003-02-15
  • 通讯作者: 张治军 E-mail:cnzhangshengmao@henu.edu.cn

Preparation and Characterization of TiO2/Poly(butyl acrylate) Nanocomposite Film

Zhang Sheng-Mao;Zhang Zhi-Jun;Dang Hong-Xin;Liu Wei-Min;Xue Qun-Ji   

  1. State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou　730000; 2Lubrication and Functional Material Laboratory, Henan University, Kaifeng　475001
  • Received:2002-05-23 Revised:2002-08-05 Published:2003-02-15
  • Contact: Zhang Zhi-Jun E-mail:cnzhangshengmao@henu.edu.cn

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摘要： 利用微乳液原位聚合法在普通玻璃表面上制备了TiO2/聚丙烯酸丁酯纳米复合膜.采用傅立叶变换红外光谱、高分辨透射电子显微镜和X射线光电子能谱对膜的结构进行了表征.结果表明， TiO2以纳米线的形式弥散在聚丙烯酸丁酯的高分子网络中，并且所制备的TiO2纳米线具有板钛矿相结构.

关键词: 原位聚合, 二氧化钛, 聚丙烯酸丁酯, 纳米复合膜

Abstract: The nano-TiO2/Poly(butyl acrylate) composite film was prepared by microemulsion in-situ polymerization method on glass substrate. The structure of the thin film was characterized by FTIR, XPS and HRTEM (high-resolution TEM) techniques. The results of FTIR analyses indicated that the poly(butyl acrylate) networks formed through in-situ polymerization. XPS results showed that Ti(OC4H9)4 changed into TiO2 through hydrolyzation. HRTEM of polymerized thin film indicated that the TiO2 nanolines are dispersed in the poly(butyl acrylate) networks.

Key words: In-situ polymerization, Titania, Poly(butyl acrylate), 　Nanocomposite film