物理化学学报 >> 1998, Vol. 14 >> Issue (01): 84-87.doi: 10.3866/PKU.WHXB19980116

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亚相金属离子与两亲配体LB膜相互作用的研究

欧阳健明, 邰子厚, 唐雯霞   

  1. 暨南大学化学系，广州 510632|南京大学配位化学所国家重点实验室，南京 210093
  • 收稿日期:1997-03-11 修回日期:1997-05-19 发布日期:1998-01-15
  • 通讯作者: 欧阳健明

XPS Study of LB Films of Amphiphilic Ligand on Surface of the Subphase Containing Metal Ions

Ouyang Jian-Ming, Tai Zi-Hou, Tang Wen-Xia   

  1. Department of Chemistry,Jinan University,Guangzhou 510632|State Key Laboratory of Coordination Chemistry,Nanjing University,Nanjing 210093
  • Received:1997-03-11 Revised:1997-05-19 Published:1998-01-15
  • Contact: Ouyang Jian-Ming

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关键词: XPS, LB膜, 金属离子, 界面, 2-十六胺基酰基-8-羟基喹啉

Abstract:

 The complex formation of 2-hexadecylcarbamoyl-8-hydroxyquinoline(HHQ) monolayers at the air/water interface by reaction with metal ions from the subphase was investigated using X-ray photoelectron spectroscopy. The formation of HHQ-metal complexes leads to the appearance of new peaks assigned to the metal ions. The information on stoichimoetry provided by XPS indicated that a metal ion is coordinated by two HHQ molecules for La3+ and Cd2+ ions, but by one HHQ molecule for Mn2+ and Ni2+ ions.

Key words: X-ray photoelectron spectroscopy, Langmuir-Blodgett(LB) Films, Metal ion, Interface, 2-hexadecylcarbamoyl-8-hydroxyquinoline