物理化学学报 >> 2005, Vol. 21 >> Issue (06): 677-680.doi: 10.3866/PKU.WHXB20050620

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溶剂中微量水对取代酞菁锌吸收光谱的影响

林梅金; 王俊东; 陈耐生; 黄金陵   

  1. 福州大学化学化工学院功能材料研究所, 结构化学国家重点实验室, 福州 350002
  • 收稿日期:2004-10-19 修回日期:2004-12-01 发布日期:2005-06-15
  • 通讯作者: 陈耐生 E-mail:nschen@fzu.edu.cn

Effect of Trace Water on Electronic Absorption Spectra of Substituted Phthalocyaninatozincs in Solvents

LIN Mei-jin; WANG Jun-dong; CHEN Nai-sheng; HUANG Jin-ling   

  1. State Key Laboratory of Structural Chemistry, Institute of Research on Functional Materials, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002
  • Received:2004-10-19 Revised:2004-12-01 Published:2005-06-15
  • Contact: CHEN Nai-sheng E-mail:nschen@fzu.edu.cn

摘要: 测定了6种烷氧基取代酞菁锌在不同溶剂中的电子吸收光谱. 在一些溶剂(如甲苯、氯仿和二氯甲烷)中, 除了存在典型的Q带吸收峰外, 在其长波长一侧还可观测到一个新的吸收峰, 结合对其荧光、核磁共振谱、添加强碱性溶剂(吡啶)以及对溶剂除水后的光谱的研究, 证实了新产生的吸收峰与溶剂中的微量水有关, 探讨了该吸收峰产生的原因.

关键词: 酞菁锌, 电子吸收光谱, 质子化

Abstract: The electronic absorption spectra of six different alkoxy substituted phthalocyaninatozincs in different solvents have been determined. It is found that a new band (named as X bands) appeared at the longer wavelength side of the Q band in some solvents, such as toluene and CH2Cl2. The band is assigned to the protonation of phthalocyaninatozincs by trace water in the solvent, and it is further proved by the fluorescence spectra and 1H NMR. By adding pyridine to the solution this X band vanishs, and by adding water to the desiccated solvent this X band recurs.

Key words: Phthalocyaninatozincs, Electronic absorption spectra, Protonation