物理化学学报 >> 1997, Vol. 13 >> Issue (03): 270-273.doi: 10.3866/PKU.WHXB19970316

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卵磷脂-水有序结构对CaCO3晶型的影响

姚松年,王春林,张操墨,熊海涛,缪炜   

  1. 武汉大学分析测试科学系，武汉 430072
  • 收稿日期:1996-07-15 修回日期:1996-10-10 发布日期:1997-03-15
  • 通讯作者: 姚松年

Influence of the Structure of the Ordered System(PC-H2O) on the Crystal Structure of CaCO3

Yao Song-Nian,Wang Chun-Lin,Zhang Cao-Mo,Xiong Hai-Tao,Miao Wei   

  1. Department of analysis and measurement science,Wuhan University,Wuhan 430072
  • Received:1996-07-15 Revised:1996-10-10 Published:1997-03-15
  • Contact: Yao Song-Nian

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关键词: 球霰石CaCO3, 生物液晶, 卵磷脂双层结构

Abstract:

 Influence of the concentration of phosphatidylcholine (PC) in the solution of 0.5mol?L-1 CaCl2 on the crystal structure of CaCO3 has been studied by means of X-ray diffraction method. When the concentration of PC is below its CMC, the calcite CaCO3 is formed. It advantageous that CaCl2 reacts with Na2CO3 so as to form vaterite CaCO3 in the lipesome composed of PC more than in the water. The arnount of vaterite CaCO3 formed is increased with increase of concentration of PC. But if the concentration of PC is so increased as to form liquid crystal, then the amount of vaterite decreases obviously. The reason for the difference of crystal type formed has been discussed in the paper.

Key words: Vaterite CaCO3, Bioliquid crystal, Structure of lecithin bilayers