物理化学学报 >> 2004, Vol. 20 >> Issue (10): 1271-1274.doi: 10.3866/PKU.WHXB20041022

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杯芳烃衍生物对K＋和电子的耦合液膜传输

毛锋旺;胡晓钧;钱洪平;姚天明;施宪法   

  1. 同济大学化学系,上海　200092; 南京大学配位化学国家重点实验室,南京　210093
  • 收稿日期:2004-03-19 修回日期:2004-06-03 发布日期:2004-10-15
  • 通讯作者: 施宪法 E-mail:xfshi@mail.tongji.edu.cn

The Liquid Membrane Coupled Transport of Electron-Cation Symport with Calixarene Derivatives and [Ni(dmit)2] Complex as Cooperating Carriers

Mao Feng-Wang;Hu Xiao-Jun;Qian Hong-Ping;Yao Tian-Ming;Shi Xian-Fa   

  1. Department of Chemistry, Tongji University, Shanghai　200092; State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing　210093
  • Received:2004-03-19 Revised:2004-06-03 Published:2004-10-15
  • Contact: Shi Xian-Fa E-mail:xfshi@mail.tongji.edu.cn

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摘要： 在文献的基础上设计了一套电子/阳离子同向耦合传输的新体系,以多硫1,2-二硫醇烯镍的配合物为电子载体,杯芳烃的酯类衍生物为阳离子载体,采用连二亚硫酸钠和铁氰化钾作为还原剂和氧化剂,成功地实现了电子/钾离子同向耦合传输.研究了电子载体和离子载体对耦合传输的影响,并对电子耦合传输的传输机理做了初步的研究.

关键词: 耦合液膜传输, 杯芳烃衍生物, [Ni(dmit)2]配合物

Abstract: A new coupled transport system, using calixarene derivatives as the cationic carriers and nickel complex of multi-sulfur 1,2-dithiolene[Ni(dmit)2] as the electron carrier, was reported in this paper. The reducting phase (source phase) contains sodium dithionite as reducing agent; the oxidation phase (receiving phase) contains potassium ferricyanide as oxidizing agent. Driven by the redox gradient, the coupled transports of electrons and metal cations were thus realized. The impacts of the cationic carriers and the electronic carrier on the coupled transport were studied. In addition, the mechanism of transport of electron-cation symport was discussed.

Key words: Liquid membrane coupled transport, Calixarene derivatives, Multi-sulfur 1,2-dithiolene complex of nickel