物理化学学报 >> 1995, Vol. 11 >> Issue (06): 488-491.doi: 10.3866/PKU.WHXB19950603
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高庆宇,林娟娟,马克勤,臧雅茹,蔡遵生,赵学庄
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Gao Qing-Yu,Lin Juan-Jun,Ma Ke-Qin,Zang Ya-Ru,Cai Zun-Sheng,Zhao Xue-Zhuang
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关键词: 非线性化学反应, CSTR, 复杂振荡, 双节律
Abstract:
Complex periodic oscillations which are associated with Farey sequences and sustained aperiodic oscillations (maybe chemical chaos) have been first observed in Hydrogen Peroxide-Potassium Thiocyanate-Cupric Sulfate System in a CSTR. When pH is high (generally at pH>9), oscillations in pH and Pt potential in solution are synchronous, and pH increases as Pt potential in solution increases; when pH is low (gernerally pH<9),oscillations in pH and Pt potential are antiphase. Birthymicity of two oscillations appears at a same condition. A sample explanation is discussed.
Key words: Nonlinear chemical reaction, CSTR, Complex oscillations, Birhythmicity
高庆宇,林娟娟,马克勤,臧雅茹,蔡遵生,赵学庄. CSTR中H2O2-KSCN-CuSO4非线性反应体系的研究[J]. 物理化学学报, 1995, 11(06): 488-491.
Gao Qing-Yu,Lin Juan-Jun,Ma Ke-Qin,Zang Ya-Ru,Cai Zun-Sheng,Zhao Xue-Zhuang. Study of the H2O2-KSCN-CuSO4 Nonlinear Chemical System in a CSTR[J]. Acta Phys. -Chim. Sin., 1995, 11(06): 488-491.
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链接本文: http://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB19950603
http://www.whxb.pku.edu.cn/CN/Y1995/V11/I06/488
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