物理化学学报 >> 1996, Vol. 12 >> Issue (11): 986-989.doi: 10.3866/PKU.WHXB19961106

研究论文 上一篇    下一篇

超临界CO2中苯甲酸与乙醇和二甲基亚砜的相互作用

柯杰,金顺子,韩布兴,闫海科,沈德言   

  1. 中国科学院化学研究所,北京 100080
  • 收稿日期:1996-04-19 修回日期:1996-08-15 发布日期:1996-11-15
  • 通讯作者: 韩布兴

FTIR Study on the Interactions between Benzoic Acid and Ethanol,Benzoic Acid and Dimethyl Sulfoxide in Supercritical CO2

Ke Jie,Jin Shun-Zi,Han Bu-Xing,Yan Hai-Ke,Shen De-Yan   

  1. Institute of Chemistry,Academia Sinica,Beijing 100080
  • Received:1996-04-19 Revised:1996-08-15 Published:1996-11-15
  • Contact: Han Bu-Xing

摘要:

在35.0℃、12.6MPa条件下,用红外光谱法研究了超临界CO2中苯甲酸与乙醇和二甲基亚砜的相互作用.结果表明,在纯超临界CO2中,苯甲酸以单体和二聚体的形式存在.体系中有乙醇或二甲基亚砜存在时,这些强极性物质与苯甲酸形成氢键缔合体,并且非缔合苯甲酸的浓度随乙醇浓度增加而减小.

关键词: 红外光谱, 苯甲酸, 乙醇, 二甲基亚砜, 二氧化碳, 超临超界流体

Abstract:

Infrared spectra of benzoic acid in CO2-ethanol and CO2-dimethyl sulfoxide(DMSO) mixed supercritical fluids have been determined at 35.0℃ and 12.6MPa. It was observed that benzoic acid exists in both forms of monomer and dimer in pure supercritical CO2. Benzoic acid begin to form hydrogen-bonded complexes with ethanol and DMSO even their concentrations are very low and the concentration of the monomer of benzoic acid decreases with increasing of ethanol concentration, provided that the total concentration of the acid is fixed.

Key words: FTIR, Benzoic Acid, Ethanol, Dimethyl Sulfoxide, CO2, Supercritical fluid