水溶性大分子调控碳酸钙结晶的研究进展

doi:10.3866/PKU.WHXB20100639

摘要/Abstract

摘要：

结合本课题组的工作综述了水溶性大分子调控碳酸钙合成的研究进展. 通过分析生物大分子、合成大分子以及大分子/表面活性剂混合体系对碳酸钙结晶习性的影响, 讨论了水溶性大分子对碳酸钙形貌和晶型的调控机理. 大分子调控碳酸钙合成的研究不仅为人们制备不同形貌、尺寸和晶型的碳酸钙开拓了思路, 也为满足不同的工业需求提供了理论指导.

关键词: 水溶性大分子, 碳酸钙, 结晶, 晶型, 形貌

Abstract:

The influence of water-soluble macromolecules on the crystallization of calcium carbonate is reviewed combining with our work. The mechanisms are interpreted based on the analysis of calcium carbonate crystallization in the presence of biomacromolecules, synthetic polymers, or mixtures of the polymer and surfactants. This paper provides not only the methods for the crystallization of calcium carbonate consisting of different resultant morphologies, polymorphs, and sizes, but also a theoretical guide for industrial production.

Key words: Water soluble polymer, Calcium carbonate, Crystallization, Polymorph, Morphology

MSC2000:

O645

杨效登, 沈强, 徐桂英. 水溶性大分子调控碳酸钙结晶的研究进展[J]. 物理化学学报, 2010, 26(08): 2087-2095.

YANG Xiao-Deng, SHEN Qiang, XU Gui-Ying. Crystallization of Calcium Carbonate Using Water-Soluble Macromolecules[J]. Acta Phys. -Chim. Sin., 2010, 26(08): 2087-2095.

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