Acta Phys. -Chim. Sin. ›› 2007, Vol. 23 ›› Issue (12): 1851-1856.doi: 10.1016/S1872-1508(07)60089-8

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Prepareration of ZrO2-TiO2-CeO2 and Its Application in the Selective Catalytic Reduction of NO with NH3

LIN Tao; LI Wei; GONG Mao-Chu; YU Yao; DU Bo; CHEN Yao-Qiang   

  1. College of Chemistry, Sichuan University, Chengdu 610064, P. R. China
  • Received:2007-07-25 Revised:2007-09-27 Published:2007-11-30
  • Contact: CHEN Yao-Qiang E-mail:nic7501@email.scu.edu.cn

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Abstract: TiO2, ZrO2-TiO2, and ZrO2-TiO2-CeO2 were prepared by co-precipitation method and characterized by X-ray diffraction (XRD), specific surface area measurements (BET), temperature-programmed desorption (NH3-TPD), oxygen storage capacity (OSC), and temperature-programmed reduction (H2-TPR). The results showed that ZrO2-TiO2-CeO2 exhibited large number of surface strong acidity, possessed some oxygen storage capacity, and strong redox property. The three materials were used as supports and the monolith catalysts were prepared with 1% (w) V2O5 and 9%(w) WO3 for selective catalytic reduction (SCR) of NO with ammonia in the presence of excessive O2, and the results of catalytic activity showed that the catalyst used ZrO2-TiO2-CeO2 as support yielded nearly 100% NO conversion at 275 ℃ at a gas hourly space velocity (GHSV) of 10000 h-1, and it had the best catalytic activity and showed great potential for practical application.

Key words: ZrO2-TiO2-CeO2, ZrO2-TiO2, TiO2, SCR, NO, NH3

MSC2000: 

  • O643