Acta Phys. -Chim. Sin. ›› 2008, Vol. 24 ›› Issue (08): 1405-1410.doi: 10.1016/S1872-1508(08)60060-1

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Preparation and Dielectric Properties of Mn-Doped Ba0.6Sr0.4TiO3-MgTiO3 Composite Ceramics

LI Ming-Li, XU Ming-Xia, LIANG Hui, LI Xiao-Lei, XU Ting-Xian   

  1. Key Laboratory for Advanced Ceramics and Machining Technology of the Ministry of Education, School of Materials Science and Engineering, Tianjin University, Tianjin 300072, P. R. China
  • Received:2008-02-29 Revised:2008-05-04 Published:2008-08-06
  • Contact: XU Ming-Xia;

Abstract: Barium strontium titanate (Ba0.6Sr0.4TiO3, BST) nano-powders were prepared using Ba(NO3)2, Sr(NO3)2, oxalic acid dehydrate, and tetrabutyl titanate (Ti(OC4H9)4) as precursors by the chemical co-precipitation method. The product was characterized by thermogravimetry-differential scanning calorimetry (TG-DSC) thermal analyses, X-ray diffraction (XRD), and scanning electron microscopy (SEM). The experimental results indicated that the resulting Ba0.6Sr0.4TiO3 nano-powders were homogeneous with agglomerated nature. The Ba0.6Sr0.4TiO3-MgTiO3 (BST-MT) bulk composite ceramics doped by Mn were obtained by the traditional solid phase method. The XRD patterns demonstrated that Mn-doped BST was unable to change the perovskite crystalline structure of BST materials. SEM photographs revealed that the crystalline grains became larger with increasing the content of doping Mn (<1.5% (x, molar fraction)) and then the size of grains decreased after the Mn content exceeded 1.5%in the BST ceramics, suggesting the effect of Mn doping on the morphologies of BST-MT composites. The dielectric properties of BST-MT composite ceramics doped with 0.1%-2.0% (x)Mn were investigated systematically. Two effects of Mn doping on the dielectric properties of the BST-MT composite ceramics were observed. At low Mn doping concentrations (<1.5%), Mn mainly acted as an acceptor dopant to replace Ti at the B site of ABO3 perovskite structure, leading to a diffused phase transition. It was also observed that the grain size increased drastically as the Mn content increased and thus caused the decrease of dielectric loss. At higherMn doping concentrations (>1.5%), the grain size decreased and the suppression of permittivity and the drastic increase of the dielectric losses were observed, which indicated a“composite”mixing effect.

Key words: Bariumstrontiumtitanate, Mn doping, Microstructure, Dielectric property


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