Acta Phys. -Chim. Sin. ›› 1986, Vol. 2 ›› Issue (03): 254-262.doi: 10.3866/PKU.WHXB19860311
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Yang Pin; Wang Yuekui
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Abstract: The complexes, Sm(TTA)_4·HP and Dy(TTA)_4·HP, have been prepared, and their UV-VIS-NIR absorption spectra measured. The matrix element expressions with I=1/2 to 15/2 of the configurations f~5 and f~9 in a D_4~* symmetry field were derived with Double Sphere Coordination Point Charge Field Model. And the influence of change in symmetry of complex unit R_EO_8 on the DSCPCF splitting of their levels was discussed. Based on theoretical ealcalation, the intra-f transition peaks in the absorption bands were assigned.
Yang Pin; Wang Yuekui. ANALYSIS OF SPECTRA OF THE SAMARIUM AND DYSPROSIUM TETRA (2-THENOYLTRIFLUO-ROACETONE) MONO PIPERIDINE COMPLEXES[J].Acta Phys. -Chim. Sin., 1986, 2(03): 254-262.
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URL: http://www.whxb.pku.edu.cn/EN/10.3866/PKU.WHXB19860311
http://www.whxb.pku.edu.cn/EN/Y1986/V2/I03/254
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