Acta Phys. -Chim. Sin. ›› 1988, Vol. 4 ›› Issue (01): 88-91.doi: 10.3866/PKU.WHXB19880118
• Note •
Xu Zheng*; Yu Yunpeng; You Xiaozeng
The equilibium constants of acid-base interaction between Mi(Octyl_dtp)_2 and alkylamine were determined by GLC method at several temperatures. Thermodynamic parameters △H and △S were evaluted as follows:ethylamine: △H=-11.5kJ mol~(-1) △S=-22.7J K~(-1) mol~(-1)diethylamine: △H=-18.1kJ mol~(-1) △S=-42.1J K~(-1) mol~(-1)The variations of logK versus temperature fit following equations:ethylamine: lgK=-1.19+598.9/Tdiethylamine: lgK=-2.20+945.6/T
Xu Zheng*; Yu Yunpeng; You Xiaozeng. THE STUDY ON THERMODYNAMIC PROPERTIES OF ADDUCT REACTIONS OF BIS-(O,O'-DIOCTYLDITHIOPHOSPHATO) NICKEL (Ⅱ) WITH ALKYLAMINE BY GLC METHOD[J].Acta Phys. -Chim. Sin., 1988, 4(01): 88-91.
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