Acta Phys. -Chim. Sin. ›› 1989, Vol. 5 ›› Issue (02): 151-155.doi: 10.3866/PKU.WHXB19890205

• ARTICLE • Previous Articles     Next Articles

HE PHASE TRANSFER OF CO(Ⅱ) CATALYZED BY 2,2′-BIPYRIDINE AT THE WATER/NITROBENZENE INTERFACE

Liu Yuqing; Wang Erkang   

  1. Changchun Instiute of Applied Chemistry; Academia Sinica
  • Received:1987-08-31 Revised:1988-05-24 Published:1989-04-15
  • Contact: Wang Erkang

Abstract: The chemical reactions coupled with the phase transfer of Co(Ⅱ) catalyzed by 2,2′ -bipyridine across the water/nitrobenzene interface have been observed by using cyclic voltammetry (CV). Coupled chemical reactions both in the organic phase or in the aqueus phase influence the CV behavior of successive complex phase transfer obviously and an irreversible phenomenon similar to that existed at the metal electrode/electrolyte solution interface was observed. For different complexes, the phase transfer mechanism is different.