Acta Phys. -Chim. Sin. ›› 1991, Vol. 7 ›› Issue (02): 219-222.doi: 10.3866/PKU.WHXB19910218
• Note •
Bian Ze-Liang; Zhang Qi-Yuan; Sun Xiang-Yu; Zhao Yao-Xing
Fast atom bombardment mass spectra of a series of arenediazonium salts with various substituents complexed with 18-crown-6 and dibenzo-24-crown-8 ethers were examined. The correlation between quasi-molecular ion abundance of various complexes and the properties, coordination ability of donor-acceptor linkages in the complexes were studied. By using molecular orbital calculation we have successfully demonstrated that the correlation cited is related to the electron cloud densities on the heteroatoms α-N and β-N of arenediazonium salts.
Crown ethers complexs,
Fast atom bombardment mass spectrometry
Bian Ze-Liang; Zhang Qi-Yuan; Sun Xiang-Yu; Zhao Yao-Xing. Investigation of Fast Atom Bombardment Mass Spectrometry of Arenediazonium Salts/Mechanism of Their Quasi-Molecular Ions[J].Acta Phys. -Chim. Sin., 1991, 7(02): 219-222.
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