Acta Phys. -Chim. Sin. ›› 1992, Vol. 8 ›› Issue (03): 358-363.doi: 10.3866/PKU.WHXB19920314

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Study of Hydrogen Bond Association of Alcohol Molecules in Alkanes by IR Quantitative Analysis

Xu Jian-He; Sun Xian-Da; Lu Wei-Qin; Gao Hong-Jin   

  1. Department of Chemistry, Tsinghua University, Beijing 100084
  • Received:1991-02-09 Revised:1991-07-30 Published:1992-06-15
  • Contact: Gao Hong-Jin

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Abstract: The IR spectra of n-C_(16)H_(33)OH/n-C_6H_(14)(n-hexadecanol/n-hexane) system in seven different alcohol concentrations (0.01-0.20 mol·L~(-1)) were measured and analysed by combined Fourier self-deconyolution and curve-fitting methods. The types of associa-tion in the system can be identified and their distribution can be evaluated.

Key words: IR quantitative analysis, Alcohol/Alkane system, Hydrogen bond association