Rh(acac)(CO)2的振动光谱及其简正坐标分析

doi:10.3866/PKU.WHXB19920421

Acta Phys. -Chim. Sin. ›› 1992, Vol. 8 ›› Issue (04): 530-535.doi: 10.3866/PKU.WHXB19920421

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Vibrational Spectrum and Normal Coordinate Analysis on Rh(acac)(CO)₂

Liu Sheng-Ming; Lin Zheng-Yan; Yin Yuan-Qi

Fuzhou Laboratory of Structural Chemistry, Academia Sinica, Fuzhou 350002; Lanzhou Institute of Chemical Physics, Academia Sinica, Lanzhou 730000

Received:1991-03-02 Revised:1991-09-11 Published:1992-08-15
Contact: Yin Yuan-Qi

Abstract

Abstract: The Raman and infrared spectra of dicarbonyl (acetylacetonato) rhodium have been measured form 4000 to 80 cm~(-1). A normal coordinate analysis was performed for all modes by using Simplified General Valence Force Field. 38 force constants were used during the calculation process. Some new assignments of bands have been made and they were supported by some proofs. The reliabilty of result was discussed.

Key words: Vibrational spectrum, Infrared spectra, Raman spectra, Normal coordinate analysis

Liu Sheng-Ming; Lin Zheng-Yan; Yin Yuan-Qi. Vibrational Spectrum and Normal Coordinate Analysis on Rh(acac)(CO)₂[J].Acta Phys. -Chim. Sin., 1992, 8(04): 530-535.

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Vibrational Spectrum and Normal Coordinate Analysis on Rh(acac)(CO)₂

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Vibrational Spectrum and Normal Coordinate Analysis on Rh(acac)(CO)₂