Acta Phys. -Chim. Sin. ›› 1992, Vol. 8 ›› Issue (04): 530-535.doi: 10.3866/PKU.WHXB19920421

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Vibrational Spectrum and Normal Coordinate Analysis on Rh(acac)(CO)2

Liu Sheng-Ming; Lin Zheng-Yan; Yin Yuan-Qi   

  1. Fuzhou Laboratory of Structural Chemistry, Academia Sinica, Fuzhou 350002; Lanzhou Institute of Chemical Physics, Academia Sinica, Lanzhou 730000
  • Received:1991-03-02 Revised:1991-09-11 Published:1992-08-15
  • Contact: Yin Yuan-Qi

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Abstract: The Raman and infrared spectra of dicarbonyl (acetylacetonato) rhodium have been measured form 4000 to 80 cm~(-1). A normal coordinate analysis was performed for all modes by using Simplified General Valence Force Field. 38 force constants were used during the calculation process. Some new assignments of bands have been made and they were supported by some proofs. The reliabilty of result was discussed.

Key words: Vibrational spectrum, Infrared spectra, Raman spectra, Normal coordinate analysis