Acta Phys. -Chim. Sin. ›› 1993, Vol. 9 ›› Issue (05): 698-701.doi: 10.3866/PKU.WHXB19930524

• Note • Previous Articles     Next Articles

Deduced Extent Method for Thermokinetics II. Thermokinetic Studies on 2-2 Type Reversible Reaction

Liu Jin-Song; Zeng Xian-Cheng; Deng Yu   

  1. Department of Chemistry, Sichuan University, Chengdu 610064
  • Received:1992-03-11 Revised:1992-08-10 Published:1993-10-15
  • Contact: Liu Jin-Song

Abstract: Thermokinetics for a 2-2 reversible reaction system, 2-nitropropane with mor-pholion, have been studied at 25 and 30 ℃ in 40% (v/v) ethyl alcohol aqueous solution by the reduced extent method.
The rate constants、equilibrium constants、activation energies、activation free-energies、activation ethalpies and activation entropies of the reversible reaction have been calculated.
The concept of the reduced extent of thermokinetics and the experimetal results have been discussed in this paper.

Key words: Thermokinetics, Reduced extent method, Reversible reaction, Calorimetry