Acta Phys. -Chim. Sin. ›› 1994, Vol. 10 ›› Issue (01): 19-21.doi: 10.3866/PKU.WHXB19940106

• Communication • Previous Articles     Next Articles

Energy Transfer Reaction of Metastable CO(α3П) Molecule with CN Radical

Ni Jin-Zhi, Li Shu-Tao, Chu Yan-Nan, Hu Yi-Hua, Cao De-Zhao   

  1. Laser Spectroscopy Laboratory, Anhui Institute of Pptics and Fine Mechanics, Academia Sinica, Hefei 230031
  • Received:1993-09-14 Revised:1900-01-01 Published:1994-01-15
  • Contact: Ni Jin-Zhi

Abstract:

Energy-transfer reaction from metastable CO(a~3П) molecule to CN radical has been studied in a room-temperature flow reactor. The CN (B-X, △v=0, ±1, ±2) violet emission bands were obtained. The △v=0 sequence of CN(B) were analyzed by computer simulation. The vibrational temperature is 3400 K. By using the reference reaction CO(a)+NO, the formation rate constant of CN(B) has been measured, k_(CN)(B)=1.1×10~(-11) cm~3·molecule~(-1)·s~(-1).

Key words: Metastable CO(a) molecule, CN radical, Energy transfer