Acta Phys. -Chim. Sin. ›› 1994, Vol. 10 ›› Issue (09): 774-778.doi: 10.3866/PKU.WHXB19940902

• ARTICLE • Previous Articles     Next Articles

Thermal Decompositon Process and the Fragmentation Regularity of FAB-Mass Spectra of the Complex [Na3Fe(C2O4)3]·5H2O

Zheng Yu, Xie Wei-Wen, Zhang Lin-Na, Fu Gui-Xiang, Yu Lu, Zhu Zi-Ying   

  1. State Key Laboratory of Structure Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002|Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032
  • Received:1993-03-17 Revised:1993-04-26 Published:1994-09-15
  • Contact: Zheng Yu

Abstract:

The thermal decomposition process of iron trisoxalato complex has been investigated by InSitu IR spectroscopy. The Products in gaseous and solid phases were analyzed and verified by gas chromatographic analysis (GC), differential thermal analysis (DTA), thermogravimetric analysis (TGA) and high temperature X-ray powder diffraction (HXRD) as well. The Fast Atom Bombaxdment (FAB) Mass Spectra of title complex were detected.

Key words: In Situ IR spectroscopy, Thermal decomposition, DTA-TGA, FAB-Mass spectra