Acta Phys. -Chim. Sin. ›› 1995, Vol. 11 ›› Issue (11): 1014-1019.doi: 10.3866/PKU.WHXB19951111

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Study on the Generated Mechanism of Carbazole Nitroxyl Radical υiα Photocatalysis Oxidation of Carbazole

Wang Su-Hua,Chen De-Wen   

  1. Institute of Chemistry,Academia Sinica,Beijing 100080,China
  • Received:1995-02-24 Revised:1995-04-19 Published:1995-11-15
  • Contact: Chen De-Wen

Abstract:

ESR and spin trapping-ESR method was used to study the photocatalytic oxidation of carbazole at surface of CdS particle. Carbazole nitroxyl radical was first obtained and its haif period is about 10 ~ 20min , g value is 2.0060. The resuts also show that the production of carbazole nitroxyl radical may be described by degenerated branch chain reaction scheme.

Key words: Carbazole, Photocatalysis, Nitroxyl radical, Chain reaction, ESR