Acta Phys. -Chim. Sin. ›› 1996, Vol. 12 ›› Issue (07): 577-580.doi: 10.3866/PKU.WHXB19960701

• ARTICLE •     Next Articles

Study on Tetraiodoterephthalato-bidged Cobalt(II) Binuclear Complexes

Miao Ming-Ming,Sun Xian-Ru,Shi Jing-Min,Cheng Peng,Laio Dai-Zheng,Jiang Zong-Hui,Wang Geng-Lin   

  1. Department of Chemistry,Nankai University,Tianjin 300071
  • Received:1995-06-30 Revised:1995-11-09 Published:1996-07-15
  • Contact: Wang Geng-Lin

Abstract:

Four novel Cobalt(Ⅱ) complexes have been synthesized and characterized, namely [Co2(4I-TPHA)(L) 4 (ClO4)2 (L denotes 1, 10-phenanthroline(phen)(1), 5-nitro1, 10-phenanthroline(NO2-phen)(2), 2,2'- bipyridyl(bpy) (3) and 4. 4'-dimethyl-2, 2'bipyridyl (Me2bpy) (4). respectively),where 4I- TPHA is the tetraiodoterephthalate dianion. The magnetic studies indicate that a weak antiferromagnetic spin exchange imteraction exists between the metal ions.

Key words: Binuclear compexes cobalt(II)-Cobalt(II), Tetraiodoterephthalate dianion, Antiferromagnetic interaction