Acta Phys. -Chim. Sin. ›› 1998, Vol. 14 ›› Issue (08): 673-675.doi: 10.3866/PKU.WHXB19980801

• Communication •     Next Articles

Study of CICOCO Free Radical

Mao Wen-Tao, Li Qiang, Su Hong-Mei, Kong Fan-Ao   

  1. State Key Laboratory of Molecular Reaction Dynamics Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080
  • Received:1998-04-01 Revised:1998-05-08 Published:1998-08-15
  • Contact: Kong Fan-Ao

Abstract:

The free radical of CICOCO has been investigated theoretically and experimentally Geometry、vibrational frequencies and dissociative energy barrier of the ground state of CICOCO were obtained by ab initio calculations. By 351 nm photolysis of (CICO)2, CICOCO's infrared emission at 1844 cm-1 was recorded by TRFTIR spectrometer.

Key words: CICOCO, Ab initio Calculation, Tr-FTIR spectroscopy