Acta Phys. -Chim. Sin. ›› 1998, Vol. 14 ›› Issue (09): 811-816.doi: 10.3866/PKU.WHXB19980909

• ARTICLE • Previous Articles     Next Articles

Luminescence Properties and Energy Transfer of Rare Earth(III) Complexes

Yu An-Chi, Ying Li-Ming, Zhao Xin-Sheng, Xia Li-Sheng, Li Qin, Huang Chun-Hui   

  1. College of Chemistry and Molecular Enginering,Peking University,Beijing 100871|State Key Laboratory of Rare Earth Materials Chemistry and Applications,Peing University,Beijing 100871
  • Received:1997-12-29 Revised:1998-03-26 Published:1998-09-15
  • Contact: Zhao Xin-Sheng

Abstract:

 The luminescence properties and energy transfer of some rare earth complexes were extensively studied by laser induced fluorescence technique at room temperature. The excitation spectra of central ion (Eu3+ ) was obtained. The excitation spectra from the triplet state and the singlet state of ligand (DBM ) were obtained. It was found that there exists a dip peak in the emission spectra of Eu(DBM )3.2H2O complex because the transition 5D3 -7F0 of the central ionEu3+ absorbs the emission of the ligand DBM (dibenzoylmethane).

Key words: Rare-earth(III) complex, Laser induced fluorescence, Energy transfer