Please wait a minute...
Acta Physico-Chimica Sinica  2000, Vol. 16 Issue (10): 952-955    DOI: 10.3866/PKU.WHXB20001016
New Ecomaterial Zireonyl Molybopyrophosphate for Cesium Removal from HLLW
Zhang Hui-Yuan, Wang Shu-Lan, Wang Rong-Shu, Lin Can-Sheng, Zhang Xian-Ye, Wang Xiao-Rong
School of Chemical engineering and Technology,Tianjin University,Tianjin 300072|Chinese Institute of Atomic Energy,Beijing 102413
Download:   PDF(2117KB) Export: BibTeX | EndNote (RIS)      


Six kinds of pyrophosphate were synthesized. The investigation on ion exchange properties showed that zireonyl molybopyrophosphate exhibited large exchange capacity and high distribution coefficient for cesium in the medium of 3 mol• L- 1 HNO3.Preliminary study of its properties indicated that this material is a bifunctional inorganic ion exchanger with good thermal and chemical stabilities. ZMPP might be suitable for removing cesium directly from strong acidic HLLW.

Key wordsCesium      HLLW      Zireonyl molybopyrophosphate      Ion exchange     
Received: 03 January 2000      Published: 15 October 2000
Corresponding Authors: Wang Rong-Shu   
Cite this article:

Zhang Hui-Yuan, Wang Shu-Lan, Wang Rong-Shu, Lin Can-Sheng, Zhang Xian-Ye, Wang Xiao-Rong. New Ecomaterial Zireonyl Molybopyrophosphate for Cesium Removal from HLLW. Acta Physico-Chimica Sinica, 2000, 16(10): 952-955.

URL:     OR

[1] WANG Quan-Jun, SUN Hong-Juan, PENG Tong-Jiang, FENG Ming-Zhu. Structure Development during the Cation Exchange Processes of Graphite Oxide[J]. Acta Physico-Chimica Sinica, 2017, 33(2): 413-418.
[2] FU Zhong-Hua, LONG Kai-Ming, LIU Xue-Mei, HAN Jun, TANG Lei. Analysis of Trace Thorium in Uranium Sample Using Isotope Dilution Mass Spectrometry[J]. Acta Physico-Chimica Sinica, 2015, 31(Suppl): 14-18.
[3] HOU Hong-Ying. Recent Research Progress in Alkaline Polymer Electrolyte Membranes for Alkaline Solid Fuel Cells[J]. Acta Physico-Chimica Sinica, 2014, 30(8): 1393-1407.
[4] LIU De-Zhi, HOU Xi-Xin, ZHU Xiu-Ling, WANG Rui, JING Jian, CUI Yue. Preparation and Physicochemical Property of Self-Crosslinked Poly(phthalazinone ether ketone) Anion-Exchange Membranes[J]. Acta Physico-Chimica Sinica, 2013, 29(12): 2573-2578.
[5] WANG Wang-Yin, PAN Ming-Xue, QIN Yu-Cai, WANG Ling-Tao, SONG Li-Juan. Effects of Surface Acidity on the Adsorption Desulfurization of Cu(I)Y Zeolites[J]. Acta Physico-Chimica Sinica, 2011, 27(05): 1176-1180.
[6] LI Sheng, QIU Yu-Bing, GUO Xing-Peng. Electrochemical Impedance of Polypyrrole Films under Different Conditions[J]. Acta Physico-Chimica Sinica, 2010, 26(03): 601-609.
[7] SUN Xiao-Li, ZENG Qing-Xuan, FENG Chang-Gen. Adsorption Kinetics of Chromium (VI) onto an Anion Exchange Fiber Containing Polyamine[J]. Acta Physico-Chimica Sinica, 2009, 25(10): 1951-1957.
[8] LOU Tai-Ping; WANG Jia-Liang. Ion Exchange Behavior of Na/Li for the Lithium Ion Conductor of LiTi2(PO4)3[J]. Acta Physico-Chimica Sinica, 2007, 23(10): 1642-1646.
[9] ZHAO Wen-Xia; HU Man-Cheng; LI Shu-Ni; JIANG Yu-Cheng; ZHANG Xiao-Lei; HU Lei; CHEN Huai-Jun. The Solubility of Ternary SystemRbBr/CsBr-CH3OH/C2H5OH-H2O at Different Temperatures[J]. Acta Physico-Chimica Sinica, 2007, 23(05): 695-700.
[10] LOU Tai-ping; LI Da-gang; DAI Hou-chen; TANG Shu-huan; XU Tie-wei; GAO Ming. The Ion Exchange Behavior of Na/Li for the Lithium Ion Conductor Li1.3Ti1.7Al0.3(PO4)3;[J]. Acta Physico-Chimica Sinica, 2005, 21(07): 782-785.
[11] Hu Xiu-Rong;Lü Guang-Lie;Gu Jian-Ming;Chen Lin-Shen. Study on the Relationship between Charge and Structure of Montmorillonite[J]. Acta Physico-Chimica Sinica, 2003, 19(12): 1171-1175.
[12] Wen Yan-Xuan;Wang Li-Sheng;Jin Zou-Mei. Simulation Study on Ion Exchange Kinetics of Magnesium Ion in Demagging Liquor of Phosphate Ore[J]. Acta Physico-Chimica Sinica, 2003, 19(10): 913-916.
[13] Lou Tai-Ping;Li Da-Gang;Pan Rong;Zhang Hui-Ping. Ion Exchange Behavior of Li2Mg2Si4O10F2, H2Mn8O16•1.4H2O and Li1.3Ti1.7Al0.3(PO4)3 in High-concentration LiCl Solution[J]. Acta Physico-Chimica Sinica, 2003, 19(09): 839-843.
[14] Li Hang, Chen Ming-Shu. Study on the Comparison of the Kinetics of Ion Diffusion and Ilon Exchange in Charged Colloid[J]. Acta Physico-Chimica Sinica, 1998, 14(03): 278-282.
[15] Jiang Ming,Fu Yi-Lu. Characterization of Cu(I)Y Zeolites Prepared by Solid-state Ion Exchange[J]. Acta Physico-Chimica Sinica, 1997, 13(09): 822-826.