Acta Phys. -Chim. Sin. ›› 2000, Vol. 16 ›› Issue (11): 968-971.doi: 10.3866/PKU.WHXB20001103

• Communication • Previous Articles     Next Articles

Assembly of Side-functional Monomers with lnorganic Nanometer Particles

Zhang Zhi-Hua, Guo Hai-Qing, Lv Mei-Hua, Liu Shu-Man, Wang Zhan-Guo   

  1. State Key Lanoratory of Rare Earth Materials and Application,College of Chemistry and Molecular Engineering,Peking University,Beijing 100871|Institute of Semiconductors ,Chinese Academy of Science,Beijing 100083
  • Received:2000-07-06 Revised:2000-09-01 Published:2000-11-15
  • Contact: Guo Hai-Qing E-mail:guohq@pku.edu.cn

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Abstract:

Monomers of methacrylate with various [[pi]][/[pi]]-conjugated were designed and prepared in our laboratory.The monomer with suitable end-group was successfully assembled with nano-scale inorganic particles to form an orderly-aligned structure than showed special optical properties,both absorption and emission band were much red-shifted compared with the monomer.A new type of organic/inorganic hybrid materials was obtained by in situ polymerization of the assembly.The hybid materials could also show special potical properties as the assembly.This might poen a new route to tune the emission color.

Key words: Side-functional monomer, Nanocomposite, Molecular assembly, Photoluminescence