Abstract:

Monomers of methacrylate with various [[pi]][/[pi]]-conjugated were designed and prepared in our laboratory.The monomer with suitable end-group was successfully assembled with nano-scale inorganic particles to form an orderly-aligned structure than showed special optical properties,both absorption and emission band were much red-shifted compared with the monomer.A new type of organic/inorganic hybrid materials was obtained by in situ polymerization of the assembly.The hybid materials could also show special potical properties as the assembly.This might poen a new route to tune the emission color.

Key words: Side-functional monomer, Nanocomposite, Molecular assembly, Photoluminescence