Acta Phys. -Chim. Sin. ›› 2000, Vol. 16 ›› Issue (12): 1086-1092.doi: 10.3866/PKU.WHXB20001206

• ARTICLE • Previous Articles     Next Articles

Study on the Coordination Polymer of Electropolyurushiol and Rare Earth

Tang Jie-Yuan, Zhang Wen-Gong, Gao Feng   

  1. Institute of Polymer Science,Fujian Teachers University,Fuzhou 350007
  • Received:2000-03-28 Revised:2000-06-19 Published:2000-12-15
  • Contact: Tang Jie-Yuan E-mail:wytang@fjtu.edu.cn

Abstract:

The coordination polymer of rare earth was prepared by the reaction of rare earth triisopropoxide(Pr,Nd,Eu) with electropolyurushiol polymerization(EPU).The structure and properties of the coordination polymer were characteized by FI-IR,Fluorescence,XPS,DMTA and AES.The results indicated that there is of coordination interaction between rare earth ion with electropolyurushilo in the coordination polymer,thus cross-link was formed.Therefore the coordination polymer was insoluble in most organic solvects,and glass.transition temperature increase and heat resistance were enhanced considerably.

Key words: Urushiol, Electrochemical polymerization, Rare earths, Coordination polymer