Acta Phys. -Chim. Sin. ›› 2000, Vol. 16 ›› Issue (12): 1110-1114.doi: 10.3866/PKU.WHXB20001209

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Synthesis,Structural Characterization and Thermal Decomposition Mechanism of {[Ag(ATO)2]ClO4}n

Zhang Jian-Guo, Zhang Tong-Lai   

  1. The 84 Laboratory,Beijing Insititute of Technology,Beijing 100081
  • Received:2000-03-27 Revised:2000-06-20 Published:2000-12-15
  • Contact: Zhang Tong-Lai E-mail:ztlbit@public.bta.net.cn

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Abstract:

A new supermolecule coordination compound of perchlorate di(4-amino-1,2,4-triazole-5-one) silver(I) was synthesized.It was characterized by element analysis,FT-IR,X-ray crystallogram and single crystal diffraction.The titled complex was also studied by means of TG-DTG and DSC under conditions of linear trmperature increase.The thermal decomposition remainders were determined by infrared spectroscopic analysis.Thermal decomposition mechanism of the title coordination compound was suggested.

Key words: Silver complex, Structural characterization, 4-amino-1,2,4-triazol-5-one(ZTO), Thermal decomposition mechanisms