非水体系中大孔交联酰胺基树脂的吸附热力学

doi:10.3866/PKU.WHXB20030304

Abstract

Abstract: The title resin was synthesized and the adsorption isotherms of phenol from cyclohexane solution were measured. Values of isosteric adsorption enthalpy, adsorption Gibbs free energy and adsorption entropy were calculated. These values implied a hydrogen-bonding adsorption mechanism. Furthermore, difference of adsorption property for phenol and o-nitrophenol from cyclohexane solution was studied, and the result was in accordance with the hydrogen-bonding mechanism.

Key words: Macroporous cross-linked poly(N-methyl-N-p-vinylbenzylacetamine) resin, Non-aqueous system, Phenols, Hydrogen-bonding, Adsorption mechanism

Huang Jian-Gou;Xu Man-Cai;Li Hai-Tao;Shi Zuo-Qing;He Bing-Lin. Adsorption Thermodynamics of Macroporous Cross-linked Poly (N-methyl-N-p- vinylbenzylacetamine) Resin for Phenols from Non-aqueous System[J].Acta Phys. -Chim. Sin., 2003, 19(03): 208-211.

[1]	Yuelu ZHU,Xinyang ZHAO,Qian WU,Ying CHEN,Jing ZHAO. Research Advances in C―H Bond Activation of Multitasking N-Phenoxyamides [J]. Acta Physico-Chimica Sinica, 2019, 35(9): 989-1004.
[2]	Zhe JIANG,Fei YU,Jie MA. Design of Graphene-based Adsorbents and Its Removal of Antibiotics in Aqueous Solution [J]. Acta Phys. -Chim. Sin., 2019, 35(7): 709-724.
[3]	Yuan JIAN,Wan-Jun MU,Ning LIU,Shu-Ming PENG. Removal of Sr²⁺ Ions by Ta-Doped Hexagonal WO₃: Zeta Potential Measurements and Adsorption Mechanism Determination [J]. Acta Phys. -Chim. Sin., 2016, 32(8): 2052-2058.
[4]	Zhi-Jian. LIAO,Zhen-Li. QIN,Si-Nan. DU,Si-Yu. LI,Guan-Hou. CHEN,Fang. ZUO,Jian-Bin. LUO. Orientational Transitions of Liquid Crystal Driven by Hydrogen-Bond Interaction at the Liquid Crystal-Aqueous Interface [J]. Acta Phys. -Chim. Sin., 2015, 31(9): 1733-1740.
[5]	QIAN Jia-Sheng, LIU Ming-Xian, GAN Li-Hua, LÜ Yao-Kang, CHEN Ling-Yan, YE Rui-Jie, CHEN Long-Wu. Synthesis and Electrochemical Performance of Microporous Carbon Using a Zinc(II)-Organic Coordination Polymer [J]. Acta Phys. -Chim. Sin., 2013, 29(07): 1494-1500.
[6]	ZHOU Liang-Chun, MENG Xiang-Guang, LI Jian-Mei, HU Wei, LIU Bo, DU Juan. Kinetics and Thermodynamics of Adsorption of Chlorophenols onto β-Cyclodextrin Modified Chitosan [J]. Acta Phys. -Chim. Sin., 2012, 28(07): 1615-1622.
[7]	TANG Jing, ZENG Qiao, CHEN Zhen-Dong, HUANG Xiang-Qian. Electrochemical Indirect Measurement for the Study of Glutathione Adsorption on Multiwalled Carbon Nanotubes and Activated Carbon [J]. Acta Phys. -Chim. Sin., 2012, 28(05): 1269-1274.
[8]	SUN Qian, WANG Jin-Ting, ZHANG Li-Min, YANG Mao-Ping. Photoinduced Electron and Hydrogen Transfer Reactions of Thioxanthone with Amines, Phenols and Alcohols [J]. Acta Phys. -Chim. Sin., 2010, 26(09): 2481-2488.
[9]	FU Hong-Yan, GAO Bao-Jiao, NIU Qing-Yuan. Adsorption Behavior and Mechanism of Grafted PMAA-HEMA/NVP Microspheres toward Lysozyme [J]. Acta Phys. -Chim. Sin., 2010, 26(02): 359-366.
[10]	ZHANG Rong; TAN Zai-You; ZHENG Dun-Sheng; LUO San-Lai; LI Hao-Ran. Molecular Dynamics Simulations on the Special System of TFE Aqueous Solution [J]. Acta Phys. -Chim. Sin., 2008, 24(03): 428-432.
[11]	WANG Jian; GAO Bao-Jiao; GUO Hao-Peng. Adsorption Mechanism of Grafting Particle PMAA/SiO₂ for Pirimicarb in Water Medium [J]. Acta Phys. -Chim. Sin., 2007, 23(12): 1905-1911.
[12]	YANG Zhong-Zhi; CUI Bao-Qiu. Dynamic Simulations of the Hydrogen-bondings on the Proximal Side of the Heme in Terms of ABEEM/MM Method [J]. Acta Phys. -Chim. Sin., 2007, 23(09): 1332-1336.
[13]	Zhu Yong-Chun, Cheng Guang-Jin, Dong Shao-Jun. The Relation Between Formal Potential and Structure of Indophenols and Molecular Mechnism of Electrooxidation [J]. Acta Phys. -Chim. Sin., 2000, 16(02): 111-115.
[14]	Cao Ya, Li Hui-Lin, Zhang Ai-Min. Studies on Adsorption of Carboxy Methyl Cellulose Based Polymeric Surfactants at Solid/Liquid lnterface [J]. Acta Phys. -Chim. Sin., 1999, 15(10): 952-955.
[15]	Zhang De-Chun, Zhang Yan-Qiu, Lu Cheng-Rong. Resonance-Assisted Intramolecular Hydrogen Bonding in Substituted Phenols [J]. Acta Phys. -Chim. Sin., 1998, 14(01): 63-67.

Adsorption Thermodynamics of Macroporous Cross-linked Poly (N-methyl-N-p- vinylbenzylacetamine) Resin for Phenols from Non-aqueous System

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Comments

Recommended 10