Acta Phys. -Chim. Sin. ›› 2004, Vol. 20 ›› Issue (08): 871-876.doi: 10.3866/PKU.WHXB20040818

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Electrochemical Oxidation for the Degradation of Organic Pollutants on a Novel PbO2 Anode

Zhou Ming-Hua;Dai Qi-Zhou;Lei Le-Cheng;Wu Zu-Cheng;Ma Chun-An;Wang Da-Hui   

  1. Institute of Environmental Engineering, Zhejiang University, Hangzhou 310027;College of Chemical Engineering and Materials, Zhejiang University of Technology, Hangzhou 310032
  • Received:2004-01-19 Revised:2004-03-15 Published:2004-08-15
  • Contact: Zhou Ming-Hua E-mail:skynumen@163.com

Abstract: A novel lead dioxide anode modified by fluorine and characterized by X-ray diffraction (XRD) and SEM, was applied to the organic degradation by using phenolic compounds as model pollutants. It was found that this anode showed good resistance to corrosion, perfect electrocatalytic activity and stability, indicating potential for future environmental application. Further, the degradation of organics was confirmed to be mainly of the hydroxyl radical mechanism by using isopropanol as radical scavenger, hence, such an oxidation process is essentially an advanced electrochemical oxidation process (AEOPs).

Key words: Electrochemical oxidation, Degradation, Lead dioxide anode modified by fluorine resin, Mechanism, AEOPs