Acta Phys. -Chim. Sin. ›› 2004, Vol. 20 ›› Issue (08S): 989-994.doi: 10.3866/PKU.WHXB200408zk15

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Homogeneous Catalytic Activation of Hetero－Carbon Bond and Its Addition to Alkynes

Hua Rui-Mao   

  1. Key Laboratory of Organic Optoelectronics ＆ Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing　100084
  • Received:2004-01-02 Revised:2004-03-15 Published:2004-08-15
  • Contact: Hua Rui-Mao E-mail:ruimao@mail.tsinghua.edu.cn

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Abstract: This paper reviews the transition metal complexes such as Ni, Pd, Pt, Rh, Cu-catalyzed activation of hetero－carbon bonds and the related catalytic addition reactions with alkynes. These new addition reactions provide one-step, atom-economic methods for the preparation of the functionalized alkenes, which have R3Si, R3Sn, RS, RSe, Cl and Br groups. The addition reactions proceed with high stereoselectivities and regioselectivities.

Key words: Transition metal complex, Hetero－Carbon bond, Activation, Addition reaction, Selectivity