Acta Phys. -Chim. Sin. ›› 2006, Vol. 22 ›› Issue (02): 131-134.doi: 10.3866/PKU.WHXB20060201

• ARTICLE •     Next Articles

The Three Pseudo-side-binary Systems in LiCl-(2ZnCl2•KCl)-(ZnCl2•2KCl) System

JIANG Li-bo;MENG Ai-hua;ZHANG Qi-yun   

  1. College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China
  • Received:2005-06-03 Revised:2005-08-02 Published:2006-01-22
  • Contact: ZHANG Qi-yun E-mail:qyzh@pku.edu.cn

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Abstract: Three pseudo-side-binary systems, LiCl-(2ZnCl2•KCl); LiCl-(ZnCl2•2KCl) and (2ZnCl2•KCl)-(ZnCl2•2KCl) in the pseudo-ternary LiCl-(2ZnCl2•KCl)-(ZnCl2•2KCl), have been investigated by visual-polythermal, DTA and XRD methods. Three new compounds were found in these systems. The ternary compound Li3K2Zn4Cl13 congruently melts at 245 ℃. The incongruent ternary compound Li12K2ZnCl16 and the binary incongruent compound K5Zn4Cl13 peritecticly melt at 432 ℃ and 249 ℃ respectively.

Key words: Phase diagram, LiCl, KCl, ZnCl2