Acta Phys. -Chim. Sin. ›› 2008, Vol. 24 ›› Issue (03): 507-512.doi: 10.3866/PKU.WHXB20080328

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Molecular Recognition of Chiral Zinc Porphyrin with Amino Acid Ester Derivatives

WANG Shu-Jun; ZANG Na; RUAN Wen-Juan; ZHU Zhi-Ang   

  1. College of Chemistry and Material Science, Langfang Teachers College, Langfang 065000, Hebei Province, P. R. China; Department of Chemistry, Nankai University, Tianjin 300071, P. R. China
  • Received:2007-10-08 Revised:2007-11-26 Published:2008-03-10
  • Contact: RUAN Wen-Juan E-mail:wjruan@nankai.edu.cn

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Abstract: Molecular recognition of chiral zinc porphyrin [p-(L-Leu)C2O-TPPZn] with amino acid ester derivatives was investigated by UV-Vis spectrophotometric titration and CD spectroscopy. The experimental results suggested that the association constant was KD>KL for amino acid ester derivatives, and then increased following the order of K(AlaOCH3)

Key words: Chiral zinc porphyrin, Amino acid ester, Molecular recognition, CD spectroscopy, Simulated annealing

MSC2000: 

  • O644