静电纺丝制备多孔碳纳米纤维及其电化学电容行为

doi:10.3866/PKU.WHXB20101203

Acta Phys. -Chim. Sin. ›› 2010, Vol. 26 ›› Issue (12): 3169-3174.doi: 10.3866/PKU.WHXB20101203

• ELECTROCHEMISTRY • Previous Articles Next Articles

Preparation of Porous Carbon Nanofibers by Electrospinning and Their Electrochemical Capacitive Behavior

ZHANG Xiao-Bo¹, CHEN Ming-Hai³, ZHANG Xiao-Gang², LI Qing-Wen³

1. College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, P. R. China;
2. College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, P. R. China;
3. Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou 215123, Jiangsu Province, P. R. China

Received:2010-07-01 Revised:2010-09-29 Published:2010-12-01
Contact: ZHANG Xiao-Gang, LI Qing-Wen E-mail:azhangxg@163.com, qwli2007@sinano.ac.cn
Supported by:
The project was supported by the National Key Basic Research Program of China (973) (2007CB209703) and National Natural Science Foundation of China (20633040, 20873064).

Abstract

Abstract:

Zinc acetate/polyacrylonitrile nanofibers were prepared by an electrospinning method. The as-prepared nanofibers were carbonized under argon and washed with acid to obtain porous carbon nanofibers. The surface morphology and microstructure of the porous carbon nanofibers were examined by scanning electron microscopy and X-ray diffraction. The surface area was found to be 413 m²·g^-1 by the Brunauer-Emmett-Teller (BET) method. The electrochemical performance of the electrodes was characterized by cyclic voltammetry and by chronopotentiogram tests. The results showed that the specific capacitance of the as-repapered carbon porous nanofiber electrode was 275 F·g^-1 under 1 A·g^-1, which is 162% higher than that of the carbon nanofibers without a porous structure.

Key words: Supercapacitor, Electrospinning, Porous carbon nanofiber

MSC2000:

O646

ZHANG Xiao-Bo, CHEN Ming-Hai, ZHANG Xiao-Gang, LI Qing-Wen. Preparation of Porous Carbon Nanofibers by Electrospinning and Their Electrochemical Capacitive Behavior[J].Acta Phys. -Chim. Sin., 2010, 26(12): 3169-3174.

References

1. Conway, B. E.; Pell,W. G. J. Power Sources, 2002, 105: 169
2. Liu, T. C.; Pell,W. G.; Conway, B. E.; Roberson, S. L. J. Electrochem. Soc., 1998, 145(6): 1882
3. Frackowiak, E. Phys. Chem. Chem. Phys., 2007, 9(15): 1774
4. Zhao, J. X. Fiber Composites, 2003, 12: 48. [赵稼祥. 纤维复合材料, 2003, 12: 48]
5. Ramakrishna, S.; Fujiwara, K.; Teo,W. E.; Lim, T, C.; Ma, Z. An introduction to electrospinning and nanofibers. Singapore:World Scientific Pub. Co. Inc., 2005: 26-30
6. Yi, S. P.; Zhang, H. Y.; Pei, L.; Zhu, Y. J.; Chen, X. L.; Xue, X. M. J. Alloy. Compd., 2006, 420: 312
7. Puretzky, A. A.; Geohegan, D. B.; Fan, X.; Pennycook, S. J. Appl. Phys. Lett., 2000, 76: 182
8. Huang, H. J.; Kajiura, H.; Murakami, Y. S.; Ata, M. Carbon, 2003, 41: 615
9. Liu, H. Y.;Wang, K. P.; Teng, H. S. Carbon, 2005, 43: 559
10. Liu, Y.; Zhan, L.; Zhang, R.; Qiao,W. M.; Liang, X. Y.; Ling, L. C. New Carbon Mater., 2007, 22: 259. [刘颖, 詹亮, 张睿, 乔文明, 柒晓怿, 凌立成. 新型炭材料, 2007, 22: 259]
11. Darrell, H. R.; Iksoo, C. Nanotechnology, 1996, 7: 216
12. Li, D.; Xia, Y. Adv. Mater., 2004, 16: 1151
13. Gu, S. Y.; Ren, J.; Vancso, G. J. J. Eur. Polym., 2005, 41: 2559
14. Peng, M.; Li, D.; Shen, L.; Chen, Y.; Zheng, Q.;Wang, H. Langmuir, 2006, 22: 9368
15. Park, S. H.; Kim, C.; Choi, Y. O.; Yang, K. S. Carbon, 2003, 41: 2655
16. Kim, C.; Park, S. H.; Lee,W. J.; Yang, K. S. Electrochim. Acta, 2004, 50: 877
17. Ra, E. J.; Raymundo-Pinero, E.; Lee, Y. H.; Beguin, F. Carbon, 2009, 47: 2984
18. Li, J.; Liu, E. H.; Li,W.; Meng, X. Y.; Tan, S. T. J. Alloy. Compd., 2009, 478: 371
19. Hyun, T. S.; Kang, J. E.; Kim, H. G.; Hong, J. M.; Kim, I. D. Electrochem. Solid State Lett., 2009, 12(12): A225
20. Guo, Q. H.; Zhou, X. P.; Li, X. Y.; Chen, S. L.; Seema, A.; Greiner, A.; Hou, H. Q. J. Mater. Chem., 2009, 19(18): 2810
21. Lewandowski, A.; Zajder, M.; Frackiwiak, E.; Beguin, F. Electrochim. Acta, 2001, 46: 2777
22. Biopo-Fonseca, I.; Accar, J.; Sarrazin, C.; Simon, P.; Fauvarque, J. F. J. Power Sources, 1999, 79: 238
23. Vincent, C. A.; Scrosati, B. Modern balleriesan introduction to electrochemical power sources. London: Arnold Publishing, 1997: 24-52
24. Li,W.; Chen, Z.; Li, J.; Chen, X.; Xuan, H.;Wang, X. Mater. Sci. Eng. A, 2008, 485: 481
25. Wang, Y.; Serrano, S.; Santiago-Avilés, J. J. Synth. Met., 2003, 138: 423
26. Lee, J.W.; Yoon, S. H.; Hyeon, T. E. Chem. Commun., 1999: 2177
27. Sawtschenko, L.; K, Jobst.; Schwarzenberg, M.; Paasch, G. Synth. Met., 1992, 47: 287
28. Sawtschenko, L.; Jobst, K.; Schwarzenberg M.;Wuckel, L.; Paasch, G. Synth. Met., 1991, 41-43: 1165
29. Kim, C.; Ngoc, B. T. N.; Yang, K. S.; Kojima, M.; Kim, Y. A.; Kim, Y. J.; Endo, M.; Yang, S. C. Adv. Mater., 2007, 19: 2341
30. Chmiola, J.; Yushin, G.; Gogotsi, Y.; Portet, C.; Simon, P.; Taberna, P. L. Science, 2006, 313: 1760
31. Levie, D. R. Electrochim. Acta, 1963, 8: 751
32. Austin, L. G.; Gagnon, E. G. J. Electrochem. Soc., 1973, 120(2): 251
33. Wang, Y. G.; Cheng, L.; Xia, Y. Y. J. Power Sources, 2006, 153: 191
34. Cao, L.; Xu, F.; Liang, Y. Y.; Li, H. L. Adv. Mater., 2004, 16: 1853

[1]	Yongli Tong, Meizhen Dai, Lei Xing, Hengqi Liu, Wanting Sun, Xiang Wu. Asymmetric Hybrid Capacitor Based on NiCo₂O₄ Nanosheets Electrode [J]. Acta Physico-Chimica Sinica, 2020, 36(7): 1903046-0.
[2]	Jiu Wang,Nanshi Wu,Tao Liu,Shaowen Cao,Jiaguo Yu. MnCo Oxides Supported on Carbon Fibers for High-Performance Supercapacitors [J]. Acta Physico-Chimica Sinica, 2020, 36(7): 1907072-0.
[3]	Nannan Guo,Su Zhang,Luxiang Wang,Dianzeng Jia. Application of Plant-Based Porous Carbon for Supercapacitors [J]. Acta Physico-Chimica Sinica, 2020, 36(2): 1903055-0.
[4]	Liping Kang,Gaini Zhang,Yunlong Bai,Huanjing Wang,Zhibin Lei,Zonghuai Liu. Two-Dimensional Nanosheet Hole Strategy and Their Assembled Materials for Supercapacitor Application [J]. Acta Physico-Chimica Sinica, 2020, 36(2): 1905032-0.
[5]	Yao Chen,George Zheng Chen. New Precursors Derived Activated Carbon and Graphene for Aqueous Supercapacitors with Unequal Electrode Capacitances [J]. Acta Physico-Chimica Sinica, 2020, 36(2): 1904025-0.
[6]	Jiayao Zhu, Yue Dong, Su Zhang, Zhuangjun Fan. Application of Carbon-/Graphene Quantum Dots for Supercapacitors [J]. Acta Physico-Chimica Sinica, 2020, 36(2): 1903052-0.
[7]	Yi Wang,Wangchen Huo,Xiaoya Yuan,Yuxin Zhang. Composite of Manganese Dioxide and Two-dimensional Materials Applied to Supercapacitors [J]. Acta Physico-Chimica Sinica, 2020, 36(2): 1904007-0.
[8]	Wenyi Liu,Linpo Li,Qiuyue Gui,Bohua Deng,Yuanyuan Li,Jinping Liu. Novel Hybrid Supercapacitors Based on Nanoarray Electrodes [J]. Acta Physico-Chimica Sinica, 2020, 36(2): 1904049-0.
[9]	Feng Wei,Honghui Bi,Shuai Jiao,Xiaojun He. Interconnected Graphene-like Nanosheets for Supercapacitors [J]. Acta Physico-Chimica Sinica, 2020, 36(2): 1903043-0.
[10]	Di Tian,Xiaofeng Lu,Weimo Li,Yue Li,Ce Wang. Research on Electrospun Nanofiber-Based Binder-Free Electrode Materials for Supercapacitors [J]. Acta Physico-Chimica Sinica, 2020, 36(2): 1904056-0.
[11]	Kang YANG,Xiaorui SHUAI,Huachao YANG,Jianhua YAN,Kefa CEN. Electrochemical Performance of Activated Graphene Powder Supercapacitors Using a Room Temperature Ionic Liquid Electrolyte [J]. Acta Phys. -Chim. Sin., 2019, 35(7): 755-765.
[12]	Feng JIN,Jing LI,Chenji HU,Houcai DONG,Peng CHEN,Yanbin SHEN,Liwei CHEN. High Performance Solid-state Battery with Integrated Cathode and Electrolyte [J]. Acta Physico-Chimica Sinica, 2019, 35(12): 1399-1403.
[13]	Xiangyan SHEN,Jianjiang HE,Ning WANG,Changshui HUANG. Graphdiyne for Electrochemical Energy Storage Devices [J]. Acta Phys. -Chim. Sin., 2018, 34(9): 1029-1047.
[14]	Hai-Yan WANG, Gao-Quan SHI. Layered Double Hydroxide/Graphene Composites and Their Applications for Energy Storage and Conversion [J]. Acta Physico-Chimica Sinica, 2018, 34(1): 22-35.
[15]	Wei-Shi DU,Yao-Kang LÜ,Zhi-Wei CAI,Cheng ZHANG. Flexible All-Solid-State Supercapacitor Based on Three-Dimensional Porous Graphene/Titanium-Containing Copolymer Composite Film [J]. Acta Phys. -Chim. Sin., 2017, 33(9): 1828-1837.

Preparation of Porous Carbon Nanofibers by Electrospinning and Their Electrochemical Capacitive Behavior

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Comments

Recommended 0