光电子成像方法研究Xe时间分辨多光子电离过程

doi:10.3866/PKU.WHXB20101220

Abstract

Abstract:

Femtosecond time-resolved multiphoton ionization dynamics of xenon was investigated using a homemade ion imaging detector. A comparison experiment comprising of the multiphoton ionization of Xe at 408 nm showed that the energy resolution of our homemade image detector was similar to that of a commercial detector. Under 272 nm femtosecond laser irradiation, photoelectrons with a kinetic energy of 1.57 and 0.26 eV, produced by three-photon ionization, corresponded to two different Xe + spin states, respectively. For the ionization at 408 nm, an additional first-order above-threshold ionization of Xe was also observed. In the two-color femtosecond time-resolved experiments, the photoelectron kinetic energy spectra varied with the delay time between the pump and the probe. The photoelectron intensities produced by 3+1' and 4'+1 two-color multiphoton ionization schedules became stronger with an increase in the degree of overlap between the two laser beams. The kinetic energy of the photoelectrons produced by one-color multiphoton ionization showed obvious red shifts, which were modulated by the second laser beam. Depopulation of the excited states was also observed upon application of the second laser beam. The red shifts in the photoelectron kinetic energy spectra reflect the time-dependent dynamical modulation process of the laser induced ponderomotive effect in an atomic system.

Key words: Time-resolved, Homemade, Ion imaging detector, Xenon, Photoelectron imaging, Ponderomotive effect, Multiphoton ionization

MSC2000:

O644

LIU Ben-Kang, WANG Yan-Qiu, WANG Li. Time-Resolved Multiphoton Ionization Process of Xenon Investigated by Photoelectron Imaging Method[J].Acta Phys. -Chim. Sin., 2010, 26(12): 3157-3162.

References

1. Bordas, C.; Dyer, M. J.; Fairfield, T.; Helm, H.; Kulander, K. C. Phys. Rev. A, 1995, 51: 3726
2. Schyja, V.; Lang, T.; Helm, H. Phys. Rev. A, 1998, 57: 3692
3. Wiehle, R.;Witzel, B. Phys. Rev. Lett., 2002, 89: 223002
4. Agostini, P.; Breger, P.; L' Huillier, A.; Muller, H. G.; Petite, G. Phys. Rev. Lett., 1989, 63: 2208
5. Vrijen, R. B.; Hoogenraad, J. H.; Muller, H. G.; Noordam, L. D. Phys. Rev. Lett., 1993, 70: 3016
6. de Boer, M. P.; Muller, H. G. J. Phys. B: At. Mol. Opt. Phys., 1994, 27: 721
7. Rottke, H.; Ludwig, J.; Sandner,W. J. Phys. B: At. Mol. Opt. Phys., 1996, 29: 1479
8. Gingras, G.; Tripathi, A.;Witzel, B. Phys. Rev. Lett., 2009, 103: 173001
9. Haber, L. H.; Doughty, B.; Leone, S. R. Phys. Rev. A, 2009, 79: 031401
10. Aron, K.; Johnson, P. M. J. Chem. Phys., 1977, 67: 5099
11. Agostini, P.; Fabre, F.; Mainfray, G.; Petite, G.; Rahman, N. K. Phys. Rev. Lett., 1979, 42: 1127
12. Freeman, R. R.; Bucksbaum, P. H.; Milchberg, H.; Darack, S.; Schumacher, D.; Geusic, M. E. Phys. Rev. Lett., 1987, 59: 1092
13. Paulus, G. G.; Nicklich,W.; Xu, H.; Lambropoulos, P.;Walther, H. Phys. Rev. Lett., 1994, 72: 2851
14. Hansch, P.;Walker, M. A.; VanWoerkom, L. D. Phys. Rev. A, 1997, 55: R2535
15. Hertlein, M. P.; Bucksbaum, P. H.; Muller, H. G. J. Phys. B: At. Mol. Opt. Phys., 1997, 30: L197
16. Böhmer, K.; Halfmann, T.; Yatsenko, L. P.; Charalambidis, C.; Horsmans, A.; Bergmann, K. Phys. Rev. A, 2002, 66: 013406
17. Stellpflug, M.; Johnsson, M.; Petrov, I. D.; Halfmann, T. Eur. Phys. J. D, 2003, 23: 35
18. Kaminski, P.;Wiehle, R.; Renard, V.; Kazmierczak, A.; Lavorel, B.; Faucher, O.;Witzel, B. Phys. Rev. A, 2004, 70: 053413
19. Gilb, S.; Torres, E. A.; Leone, S. R. J. Phys. B: At. Mol. Opt. Phys., 2006, 39: 4231 3161
20. Loh, Z. H.; Khalil, M.; Correa, R. E.; Santra, R.; Buth, C.; Leone, S. R. Phys. Rev. Lett., 2007, 98: 143601
21. Solomon, J. J. Chem. Phys., 1967, 47: 889
22. Chandler, D.W.; Houston, P. L. J. Chem. Phys., 1987, 87: 1445
23. Eppink, A. T. J. B.; Parker, D. H. Rev. Sci. Instrum., 1997, 68: 3477
24. Smith, L. M.; Keefer, D. R.; Sudharsanan, S. I. J. Quant. Spectrosc. Radiat. Transfer., 1988, 39: 367
25. Bordas, C.; Paulig, F.; Helm, H.; Huestis, D. L. Rev. Sci. Instrum., 1996, 67: 2257
26. Zhu, J. Y.;Wang, B. X.; Guo,W.;Wang, Y. Q.;Wang, L. Chin. Phys. Lett., 2007, 24: 1922
27. Stolow, A.; Bragg, A. E.; Neumark, D. M. Chem. Rev., 2004, 104: 1719
28. Wang, B. X.; Liu, B. K.;Wang, Y. Q.;Wang, L. Phys. Rev. A, 2010, 81: 043421
29. Saloman, E. B. J. Phys. Chem. Ref. Data, 2004, 33: 765
30. Agostini, P.; Kupersztych, J.; LompréL, A.; Petite, G.; Yergeau, F. Phys. Rev. A, 1987, 36: 4111
31. Micheal, D. P.; Landen, O. L. Phys. Rev. A, 1988, 38: 2815
32. Schmidt, T.W.; Lopez-Martens, R. B.; Roberts, G. J. Phys. B: At. Mol. Opt. Phys., 2004, 37: 1125
33. Schmitt, M.; Lochbrunner, S.; Shaffer, J. P.; Larsen, J. J.; Zgierski, M. Z.; Stolow, A. J. Chem. Phys., 2001, 114: 1206

[1]	Ning-Liang LIU,Huan SHEN. Multiphoton Dissociation and Ionization Dynamics of Allyl Chloride Using Femtosecond Laser Pulses [J]. Acta Phys. -Chim. Sin., 2017, 33(3): 500-505.
[2]	Jin-You LONG,Zhi-Ming LIU,Xue-Jun QIU,Bing ZHANG. Ultrafast Nonadiabatic Dynamics of Electronically Excited 2-Methyl Furan [J]. Acta Phys. -Chim. Sin., 2017, 33(3): 506-512.
[3]	Xiang-Kun WU,Zhi GAO,Tong-Po YU,Xiao-Guo ZHOU,Shi-Lin LIU. S(³P) Fragmentation Channel of Carbonyl Sulfide at 230 nm [J]. Acta Phys. -Chim. Sin., 2017, 33(10): 2004-2012.
[4]	Xiao-Ying. LI,Li. WANG,Yan-Qiu. WANG,Zhe. SONG,Ben-Kang. LIU. Dynamics of Excited o-Dichlorobenzene [J]. Acta Phys. -Chim. Sin., 2015, 31(9): 1655-1661.
[5]	Huan. SHEN,Bing. ZHANG. Ultrafast Dynamics of Benzene on the S₂ State Investigated by Femtosecond Time-Resolved Photoelectron Spectroscopy [J]. Acta Phys. -Chim. Sin., 2015, 31(9): 1662-1666.
[6]	SUN Zhong-Fa, GAO Zhi, WU Xiang-Kun, TANG Guo-Qiang, ZHOU Xiao-Guo, LIU Shi-Lin. Excitation Spectra and Photodissociation Dynamics of the B²П State of the N₂O⁺ Ion [J]. Acta Phys. -Chim. Sin., 2015, 31(5): 829-835.
[7]	ZHU De-Hua, ZHONG Rong, CAO Yu, PENG Zhi-Hui, FENG Ai-Xin, XIANG Wei-Dong, ZHAO Jia-Long. Size-Dependent Electron Injection and Photoelectronic Properties of CuInS₂ Quantum Dot Sensitized Solar Cells [J]. Acta Phys. -Chim. Sin., 2014, 30(10): 1861-1866.
[8]	ABULIMITI Bumaliya, ZHU Rong-Shu, QIU Xue-Jun, QIN Chen, ZHANG Bing. Studies of Ultrafast Dynamics of 3-Picoline with Femtosecond Time-Resolved Photoelectron Imaging [J]. Acta Phys. -Chim. Sin., 2014, 30(1): 22-27.
[9]	LV Yong-Gang, LI Zhi-Jun, WU Li-Zhu, WANG Peng, FU Li-Min, ZHANG Jian-Ping. Application of Time-Resolved Coherent Anti-Stokes Raman Scattering Technique on the Study of Photocatalytic Hydrogen Production Kinetics [J]. Acta Phys. -Chim. Sin., 2013, 29(08): 1632-1638.
[10]	DING Zhong-Hua, QIU Xue-Jun, XU Yan-Qi, WANG Yan-Mei, ZHANG Bing. Ultrafast Internal Conversion Dynamics of Benzyl Chloride by Femtosecond Time-Resolved Photoelectron Imaging [J]. Acta Phys. -Chim. Sin., 2012, 28(12): 2761-2766.
[11]	JIANG Li-Lin, LIU Wei-Long, SONG Yun-Fei, HE Xing, WANG Yang, WU Hong-Lin, YANG Yan-Qiang. Fluorescence and Raman Spectroscopic Characteristics of the Photo-Induced Electron Transfer of Coumarin 343 Dye-Sensitized TiO₂ Nanoparticles [J]. Acta Phys. -Chim. Sin., 2012, 28(12): 2953-2957.
[12]	GHAZAl Ahmed-Yousif, QIU Xue-Jun, QIN Chao-Chao, LONG Jin-You, ABULIMITI Bumaliya, ZHANG Bing. Ultrafast Internal Conversion Dynamics of 2-Chloropyridine by Femtosecond Time-Resolved Photoelectron Imaging [J]. Acta Phys. -Chim. Sin., 2012, 28(11): 2543-2548.
[13]	ZHANG Rong-Rong, QIN Chao-Chao, LONG Jin-You, YANG Ming-Hui, ZHANG Bing. Ultrafast Predissociation Dynamics of Excited State of Acrylic Acid [J]. Acta Phys. -Chim. Sin., 2012, 28(03): 522-527.
[14]	ZHANG Rong-Jun, QI Zhi-Mei, ZHANG Zhe. In situ Study of Self Assembly of Gold Nanoparticles and Cytochrome c by Polarized Optical Waveguide Spectroscopy [J]. Acta Phys. -Chim. Sin., 2011, 27(07): 1757-1762.
[15]	DENG Lin, QI Zhi-Mei. Effect of Glass Silylation on the Adsorption Behavior of Rhodamine 6G and Methylene Blue [J]. Acta Phys. -Chim. Sin., 2010, 26(07): 1923-1928.

Time-Resolved Multiphoton Ionization Process of Xenon Investigated by Photoelectron Imaging Method

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Comments

Recommended 0