壳聚糖修饰的NiB非晶态合金的制备及表征

doi:10.3866/PKU.WHXB20110342

Acta Phys. -Chim. Sin. ›› 2011, Vol. 27 ›› Issue (04): 953-958.doi: 10.3866/PKU.WHXB20110342

• CATALYSIS AND SURFACE SCIENCE • Previous Articles Next Articles

Preparation and Characterization of NiB Amorphous Alloy Modified Using Chitosan

WU Mei-Xia^1,2, LI Wei¹, ZHANG Ming-Hui¹, TAO Ke-Yi¹

1. Institute of New Catalytic Materials Science, College of Chemistry, Nankai University, Tianjin 300071, P. R. China;
2. Department of Chemistry, Shanxi Datong University, Datong 037009, Shanxi Province, P. R. China

Received:2010-11-11 Revised:2011-01-02 Published:2011-03-29
Contact: WU Mei-Xia, LI Wei E-mail:weili@nankai.edu.cn; wmxiccas@iccas.ac.cn
Supported by:
The project was supported by the National Natural Science Foundation of China (21073098), Research Found for the Doctoral Program of Higher Education, China (20090031110015), and Program for New Century Excellent Talents in University, China (NCET-10-0481).

Abstract

Abstract:

NiB amorphous alloy catalyst (NiB-CS) was prepared by direct reduction using the chemical- reduction method with chitosan as a stabilizer. The amorphous structure, atomic composition, and particle size of the as-prepared catalysts were characterized by X-ray diffraction (XRD), inductively coupled plasma spectrometry (ICP), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), and selected area electron diffraction (SAED). The catalytic behavior during the hydrogenation of furfuryl alcohol (FA) to tetrafurfural alcohol (THFA) was studied and compared with the NiB catalyst prepared without chitosan. The amorphous NiB-CS catalyst was found to be more reactive than the NiB catalyst. The superior catalytic activity of the NiB-CS catalyst is attributed to the small NiB particles and the high surface content of Ni active species.

Key words: Hydrogenation, Chitosan, Amorphous alloy, NiB-CS

MSC2000:

O643

WU Mei-Xia, LI Wei, ZHANG Ming-Hui, TAO Ke-Yi. Preparation and Characterization of NiB Amorphous Alloy Modified Using Chitosan[J].Acta Phys. -Chim. Sin., 2011, 27(04): 953-958.

References

(1) Schwarz, J. A.; Contescu, C.; Contescu, A. Chem. Rev. 1995, 95, 477.
(2) Sataporn, K.; Okorn, M.; Piyasan, P.; Joongjai, P. Catal. Commun. 2008, 10, 86.
(3) Wonterghem, J. V.; Morup, S.; Koch, C. J. W.; Charles, S. W.; Wells, S. Nature 1986, 32, 622.
(4) Lu, H. H.; Yin, H. B.; Dai, W. L.; Wang, W. Catal. Commun. 2008, 10, 313.
(5) Wang, M. W.; Li, F. Y.; Zhang, R. B. Catal. Today 2004, 93-95,603.
(6) Chen, X. Y.; Wang, S. A.; Zhuang, J. H. J. Catal. 2004, 227, 419.
(7) Fang, J.; Chen, X. Y.; Liu, B. J. Catal. 2005, 229, 97.
(8) Chen, X. Y.; Lou, Z. Y.; Xie, S. H. Chem. Lett. 2006, 35, 390.
(9) Liu, Y. C.; Huang, C. Y.; Chen, Y. W. J. Nanopart. Res. 2006, 8, 223.
(10) Wu, Z. J.; Zhang, M. H.; Ge, S. H.; Zhang, Z. L.; Li, W.; Tao, K. Y. J. Mater. Chem. 2005, 15, 4928
(11) Collier, P. J.; Iggo, J. A.; Whyman, R. J. Mol. Catal. A 1999, 146, 149.
(12) Reetz, M. T.; Helbig, W. J. Am. Chem. Soc. 1994, 116, 7401.
(13) Liu, M.; Yu, W.; Liu, H. J. Mol. Catal. A 1999, 138, 295.
(14) Kurihara, L. K.; Chow, G. M.; Schoen, P. E. Nanostruct. Mater. 1995, 5, 607.
(15) Ishizuki, N.; Torigoe, K.; Esumi, K.; Meguro, K. Colloids Surf. 1991, 55, 15.
(16) Yuan, G. L.; Yin, M. Y.; Jiang, T. T.; Huang, M. Y.; Jiang, Y. Y. J. Mol. Catal. A: Chem. 2000, 159, 45.
(17) Guibal, E. Pro. Polym. Sci. 2005, 30, 71.
(18) Anastas, P. T.; Warner, J. C. Green Chemistry: Theory and Practice; Oxford University Press: New York, 1998; pp 106-122.
(19) Wu, L. Q.; Lee, K.; Wang, X.; English, D. S.; Losert, W.; Payne, G. F. Langmuir. 2005, 21, 3641.
(20) Yonezawa, Y.; Kawabata, I.; Sato, T. Ber. Bunsen-Ges. Phys. Chem. 1996, 100, 39.
(21) Huang, H., Yang, X. Biomacromolecules 2004, 5, 2340.
(22) Song, Y.; Li, W.; Wang, Z. Y.; Sun, L. L.; Zhang, M. H.; Tao, K.Y. J. Fuel. Chem. Technol. 2006, 34, 483.
[宋云, 李伟, 王镇宇, 孙丽丽, 张明慧, 陶克毅. 燃料化学学报, 2006, 34, 483.]
(23) Wu, Z. J.; Ge, S. H.; Zhang, M. H.; Tao, K.Y.; Li, W. J. Colloid Interface Sci. 2009, 330, 359.
(24) Wang, L. J.; Li, W.; Zhang, M. H.; Tao, K.Y. Appl. Catal. A 2004, 259,185
(25) He, Y. G.; Qiao, M. H.; Hu, H. R.; Deng, J. F.; Fan, K. N. Appl. Catal. A 2002, 228, 29.
(26) Lu, Y. H.; Zhang, M. H.; Li, W.; Tao, K. Y.; Xue, Y. Z. Petrochem. Tech. 2005, 34, 523.
[卢银花, 张明慧, 李伟, 陶克毅, 薛永珍, 石油化工, 2005, 34, 523.]
(27) Ge, S. H.; Wu, Z. J.; Zhang, M. H.; Li, W.; Tao, K.Y. Ind. Eng. Chem. Res. 2006, 45, 2229.
(28) Legrand, J.; Taleb, A.; Gota, S.; Guittet, M. J.; Petit, C. Langmuuir 2002, 18, 4131.
(29) Chen, Y. Z.; Liaw, B. J.; Chiang, S. J. Appl. Catal. A 2005, 284, 97.

[1]	Ying Liu, Xiaofang Liu, Lin Xia, Chaojie Huang, Zhaoxuan Wu, Hui Wang, Yuhan Sun. Methanol Synthesis by CO_x Hydrogenation over Cu/ZnO/Al₂O₃ Catalyst via Hydrotalcite-Like Precursors: the Role of CO in the Reactant Mixture [J]. Acta Phys. -Chim. Sin., 2022, 38(3): 2002017-.
[2]	Zhicong Sun, Ergui Luo, Qinglei Meng, Xian Wang, Junjie Ge, Changpeng Liu, Wei Xing. High-Performance Palladium-Based Catalyst Boosted by Thin-Layered Carbon Nitride for Hydrogen Generation from Formic Acid [J]. Acta Phys. -Chim. Sin., 2022, 38(3): 2003035-.
[3]	Yanqiu Wang, Zixin Zhong, Tangkang Liu, Guoliang Liu, Xinlin Hong. Cu@UiO-66 Derived Cu⁺-ZrO₂ Interfacial Sites for Efficient CO₂ Hydrogenation to Methanol [J]. Acta Phys. -Chim. Sin., 2021, 37(5): 2007089-.
[4]	Kaimin Hua, Xiaofang Liu, Baiyin Wei, Shunan Zhang, Hui Wang, Yuhan Sun. Research Progress Regarding Transition Metal-Catalyzed Carbonylations with CO₂/H₂ [J]. Acta Phys. -Chim. Sin., 2021, 37(5): 2009098-.
[5]	Congming Li, Kuo Chen, Xiaoyue Wang, Nan Xue, Hengquan Yang. Understanding the Role of Cu/ZnO Interaction in CO₂ Hydrogenation to Methanol [J]. Acta Phys. -Chim. Sin., 2021, 37(5): 2009101-.
[6]	Jian Zhang, Liang Wang, Zhiyi Wu, Chengtao Wang, Zerui Su, Feng-Shou Xiao. Rational Design of a Core-Shell Rh@Zeolite Catalyst for Selective Diene Hydrogenation [J]. Acta Phys. -Chim. Sin., 2020, 36(9): 1912001-.
[7]	Zhen WANG,En LI,Zhiqi HE,Jiean CHEN,Yong HUANG. Dehydrogenative Annulation of γ, δ-Unsaturated Amides and Alkynes via Double C―H Activation [J]. Acta Physico-Chimica Sinica, 2019, 35(9): 906-912.
[8]	Xiaoyue MU,Lu LI. Photo-Induced Activation of Methane at Room Temperature [J]. Acta Physico-Chimica Sinica, 2019, 35(9): 968-976.
[9]	Fushan CHEN,Songlin ZHAO,Tao YANG,Taotao JIANG,Jun NI,Qunfeng ZHANG,Xiaonian LI. Highly Efficient Oxidative Dehydrogenation Aromatization of 1, 2, 3, 4-Tetrahydroquinoline by Cu2-MnO_x Catalyst [J]. Acta Physico-Chimica Sinica, 2019, 35(7): 775-786.
[10]	Yazhi YIN,Bing HU,Guoliang LIU,Xiaohai ZHOU,Xinlin HONG. ZnO@ZIF-8 Core-Shell Structure as Host for Highly Selective and Stable Pd/ZnO Catalysts for Hydrogenation of CO₂ to Methanol [J]. Acta Phys. -Chim. Sin., 2019, 35(3): 327-336.
[11]	Yanfang LIU,Bing HU,Yazhi YIN,Guoliang LIU,Xinlin HONG. One-Pot Surfactant-Free Synthesis of Transition Metal/ZnO Nanocomposites for Catalytic Hydrogenation of CO₂ to Methanol [J]. Acta Phys. -Chim. Sin., 2019, 35(2): 223-229.
[12]	Yunnan GAO,Shizhen LIU,Zhenqing ZHAO,Hengcong TAO,Zhenyu SUN. Heterogeneous Catalysis of CO₂ Hydrogenation to C₂₊ Products [J]. Acta Phys. -Chim. Sin., 2018, 34(8): 858-872.
[13]	Tian LIU,Jun LI,Weijia LIU,Yudan ZHU,Xiaohua LU. Simple Ligand Modifications to Modulate the Activity of Ruthenium Catalysts for CO₂ Hydrogenation: Trans Influence of Boryl Ligands and Nature of Ru―H Bond [J]. Acta Phys. -Chim. Sin., 2018, 34(10): 1097-1105.
[14]	Hong-Yan NING,Qi-Lei YANG,Xiao YANG,Ying-Xia LI,Zhao-Yu SONG,Yi-Ren LU,Li-Hong ZHANG,Yuan LIU. Carbon Fiber-supported Rh-Mn in Close Contact with Each Other and Its Catalytic Performance for Ethanol Synthesis from Syngas [J]. Acta Phys. -Chim. Sin., 2017, 33(9): 1865-1874.
[15]	Bo HAN,Han-Song CHENG. Nickel Family Metal Clusters for Catalytic Hydrogenation Processes [J]. Acta Phys. -Chim. Sin., 2017, 33(7): 1310-1323.

Preparation and Characterization of NiB Amorphous Alloy Modified Using Chitosan

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0