Acta Phys. -Chim. Sin. ›› 2011, Vol. 27 ›› Issue (05): 1195-1200.doi: 10.3866/PKU.WHXB20110425

• PHOTOCHEMISTRY AND RADIATION CHEMISTRY • Previous Articles     Next Articles

Photoluminescence and Electroluminescence of the Novel Soluble Zinc Phthalocyanine

BAI Qing-Long1,2, ZHANG Chun-Hua2, CHENG Chuan-Hui1, LI Wan-Cheng3, SHEN Ren-Sheng1, DU Guo-Tong1,3   

  1. 1. School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024, Liaoning Province, P. R. China;
    2. College of Chemistry and Chemical Engineering, Inner Mongglia University for Nationalities, Tongliao 028043, Inner Mongglia, P. R. China;
    3. State Key Laboratory of Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, Changchun 130021, P. R. China
  • Received:2010-11-02 Revised:2011-01-04 Published:2011-04-28
  • Contact: CHENG Chuan-Hui, Du Guo-Tong E-mail:chengch79@yahoo.cn; dugt@dlut.edu.cn
  • Supported by:

    The project was supported by the National Natural Science Foundation of China (60807009), Fundamental Research Funds for the Central Universities, China and Specialized Research Fund for the Doctoral Program of Higher Education, China (200801411038).

Abstract:

α(β)-tetra-(methoxy-phenoxy)-zinc phthalocyanine are synthesized by employing 3(4)- nitrobenzene-1,2-dicarbonitrile as precursors. They are characterized by spectrum methods and elemental analysis. The UV-Vis spectrum, photoluminescence spectra of spin-coated film and solid pellet are compared. The electroluminescent devices are fabricated by using spin coating. The results indicate that the fluorescence of solid phthalocyanine has a red-shift of more than 145 nm compared to that in solution. The fluorescences are broader in solid state than that in solution. The fluorescence of β-substituted phthalcyanines has a more red-shift than α-substituted phthalcyanines. The electroluminescent spectra around 856 and 862 nm are consisted with the photoluminescence spectra of spin-coated film. The shorter inter-molecule space leads to the large red-shift of the fluorescence.

Key words: Soluble phthalocyanine, Synthesis, Photoluminescence, Electroluminescence, Red-shift

MSC2000: 

  • O644