有机胺修饰具有较大孔径介孔材料的二氧化碳吸附性能

doi:10.3866/PKU.WHXB201202071

Abstract

Abstract: Mesoporous silica SBA-15-like materials with large pores were synthesized using tri-block copolymer P123 as a structure-directing agent, tetramethoxysilane as the silicon source, and different organic solvents as swelling agents. The resulting materials were characterized by powder X-ray diffraction (XRD), N₂ adsorption-desorption, scanning electron microscopy (SEM), and Fourier transform infrared (FTIR) spectroscopy. The results showed that the introduction of swelling agents effectively enlarged the pore diameter and pore volume of the SBA-15 materials, and pore swelling with isooctane was larger than that with CCl4. When modified with tetraethylenepentamine (TEPA), all of these composite materials exhibited excellent adsorption capacities for CO₂. The adsorption capacity of CO₂ was independent of the pore structure, if the template was removed before modification with TEPA. By contrast, the adsorption capacity increased with the pore diameter when the as-synthesized mesoporous material was modified with TEPA. The effects of temperature and pressure on the CO₂ adsorption capacity were investigated using adsorption isotherms and CO₂ temperature-programmed desorption (TPD). With CO₂ adsorption at higher temperature, the composite materials showed different adsorption capacities with pressure variation. As a result, the adsorption and separation of CO₂ on these TEPA modified mesoporous materials in ambient air flow can be realized via pressure swing adsorption.

Key words: Swelling agent, Mesoporous materials, CO₂, Pressure swing adsorption, Template, Tetraethylenepentamine

MSC2000:

O647

ZHAO Hui-Min, LIN Dan, YANG Gang, CHUN Yuan, XU Qin-Hua. Adsorption Capacity of Carbon Dioxide on Amine Modified Mesoporous Materials with Larger Pore Sizes[J].Acta Phys. -Chim. Sin., 2012, 28(04): 985-992.

References

(1) Lacis, A. A.; Schmidt, G. A.; Rind, D.; Ruedy, R. A. Science 2010, 330, 356.

(2) Melillo, J. M.; Mcguire, A. D.; Kicklighter, D.W.; Moore, B.; Vorosmarty, C. J.; Schloss, A. L. Nature 1993, 363, 234.

(3) Millward, A. R.; Yaghi, O. M. J. Am. Chem. Soc. 2005, 127, 17998.

(4) Kim, J.; Yang, S. T.; Choi, S. B.; Sim, J.; Kim, J.; Ahn,W. S. J. Mater. Chem. 2011, 21, 3070.

(5) An, J.; Rosi, N. L. J. Am. Chem. Soc. 2010, 132, 5578.

(6) Veawab, A.; Tontiwachwuthikul, P.; Chakma, A. Ind. Eng. Chem. Res. 1999, 38, 3917.

(7) Xu, X.; Song, C.; Andresen, J. M.; Miller, B. G.; Scaroni, A.W. Energy Fuels 2002, 16, 1463.

(8) Xu, X.; Song, C.; Miller, B. G.; Scaroni, A.W. Ind. Eng. Chem. Res. 2005, 44, 8113.

(9) Liu, Y. M.; Shi, J. J.; Chen, J.; Ye, Q.; Pan, H.; Shao, Z. H.; Shi, Y. Microporous Mesoporous Mat. 2010, 134, 16.

(10) Choi, S.; Drese, J. H.; Jones, C.W. ChemSusChem 2009, 2, 796.

(11) Peter, J. E.; Harlick, Abdelhamid, S. Ind. Eng. Chem. Res. 2006, 45, 3248.

(12) Sayari, A.; Belmabkhout, Y. J. Am. Chem. Soc. 2010, 132, 6312.

(13) Zhao, H. L.; Hu, J.;Wang, J. J.; Zhou, L. H.; Liu, H. L. Acta Phys. -Chim. Sin. 2007, 23, 801. [赵会玲, 胡军, 汪建军, 周丽绘, 刘洪来. 物理化学学报, 2007, 23, 801.]

(14) Chen, C.; Yang, S. T.; Ahn,W. S.; Ryoo, R. Chem. Commun. 2009, 3627.
(15) Qi, G.;Wang, Y.; Estevez, L.; Duan, X.; Anako, N.; Park, A. A.; Li,W.; Jones, C.W.; Giannelis, E. P. Environ. Sci. Technol. 2011, 4, 444.
(16) Yue, M. B.; Chun, Y.; Cao, Y.; Dong, X.; Zhu, J. H. Adv. Funct. Mater. 2006, 16, 1717.

(17) Yue, M. B.; Sun, L. B.; Cao, Y.;Wang, Y.;Wang, Z. J.; Zhu, J. H. Chem. Eur. J. 2008, 14, 3442.

(18) Yue, M. B.; Sun, L. B.; Cao, Y.;Wang, Z. J.;Wang, Y.; Yu, Q.; Zhu, J. H. Microporous Mesoporous Mat. 2008, 114, 74.

(19) Wen, J. J.; Gu, F. N.;Wei, F.; Zhou, Y.; Lin,W. G.; Yang, J.; Yang, J. Y.;Wang, Y.; Zou, Z. G.; Zhu, J. H. J. Mater. Chem. 2010, 20, 2840.

(20) Ma, L.; Han, K. K.; Ding, X. H.; Chun, Y.; Zhu, J. H. J. Nanosci. Nanotechnol. 2011, 11, 4079.

(21) Beck, J. S.; Vartuli, J. C.; Roth,W. J.; Leonowicz, M. E.; Kresge, C. T.; Schmitt, K. D.; Chu, C. T.W.; Olson, D. H.; Sheppard, E.W.; McCullen, S. B.; Higgins, J. B.; Schlenker, J. L. J. Am. Chem. Soc. 1992, 114, 10834.

(22) Zhao, D.; Feng, J.; Huo, Q.; Melosh, N.; Fredrickson, G. H.; Chmelka, B. F.; Stucky, G. D. Science 1998, 279, 548.

(23) Liu, J.; Li, C.; Yang, Q.; Yang, J.; Li, C. Langmuir 2007, 23, 7255.

(24) Sun, R. Q.; Zhou, X.; Sun, L. B.;Wu, H.; Chun, Y.; Xu, Q. H. Chem. J. Chin. Univ. 2007, 28, 2333. [孙瑞琴, 周徐, 孙林兵, 吴昊, 淳远, 须沁华. 高等学校化学学报, 2007, 28, 2333.]
(25) Hiyoshi, N.; Yogo, K.; Yashima, T. Microporous Mesoporous Mat. 2005, 84, 357.

(26) Yan, X.; Zhang, L.; Zhang, Y.; Yang, G.; Yan, Z. Ind. Eng. Chem. Res. 2011, 50, 3220.

(27) Cavenati, S.; Grande, C. A.; Rodrigues, A. E. J. Chem. Eng. Data 2004, 49, 1095.

[1]	Hengchang LIU,Yujun FENG. CO₂-Induced Interaction between a Pentablock Nonionic Copolymer and an Anionic Fluorocarbon Surfactant [J]. Acta Phys. -Chim. Sin., 2019, 35(4): 408-414.
[2]	Yazhi YIN,Bing HU,Guoliang LIU,Xiaohai ZHOU,Xinlin HONG. ZnO@ZIF-8 Core-Shell Structure as Host for Highly Selective and Stable Pd/ZnO Catalysts for Hydrogenation of CO₂ to Methanol [J]. Acta Phys. -Chim. Sin., 2019, 35(3): 327-336.
[3]	Yanfang LIU,Bing HU,Yazhi YIN,Guoliang LIU,Xinlin HONG. One-Pot Surfactant-Free Synthesis of Transition Metal/ZnO Nanocomposites for Catalytic Hydrogenation of CO₂ to Methanol [J]. Acta Phys. -Chim. Sin., 2019, 35(2): 223-229.
[4]	Mingyu ZHAO,Lin ZHU,Bowen FU,Suhua JIANG,Yongning ZHOU,Yun SONG. Sodium Ion Storage Performance of NiCo₂S₄ Hexagonal Nanosheets [J]. Acta Phys. -Chim. Sin., 2019, 35(2): 193-199.
[5]	Hui NING,Wenhang WANG,Qinhu MAO,Shirui ZHENG,Zhongxue YANG,Qingshan ZHAO,Mingbo WU. Catalytic Electroreduction of CO₂ to C₂H₄ Using Cu₂O Supported on 1-Octyl-3-methylimidazole Functionalized Graphite Sheets [J]. Acta Phys. -Chim. Sin., 2018, 34(8): 938-944.
[6]	Xiaomeng CHENG,Dongxia JIAO,Zhihao LIANG,Jinjin WEI,Hongping LI,Junjiao YANG. Self-Assembly Behavior of Amphiphilic Diblock Copolymer PS-b-P4VP in CO₂-Expanded Liquids [J]. Acta Phys. -Chim. Sin., 2018, 34(8): 945-951.
[7]	Yunnan GAO,Shizhen LIU,Zhenqing ZHAO,Hengcong TAO,Zhenyu SUN. Heterogeneous Catalysis of CO₂ Hydrogenation to C₂₊ Products [J]. Acta Phys. -Chim. Sin., 2018, 34(8): 858-872.
[8]	Tian LIU,Jun LI,Weijia LIU,Yudan ZHU,Xiaohua LU. Simple Ligand Modifications to Modulate the Activity of Ruthenium Catalysts for CO₂ Hydrogenation: Trans Influence of Boryl Ligands and Nature of Ru―H Bond [J]. Acta Phys. -Chim. Sin., 2018, 34(10): 1097-1105.
[9]	Yun-Peng GUO,Jie FENG,Wen-Ying LI. Effect of Ni Doping on Electron Transfer in Ni/MgO Catalysts [J]. Acta Phys. -Chim. Sin., 2017, 33(9): 1796-1802.
[10]	Liang ZHOU,Xue-Hua ZHANG,Lin LIN,Pan LI,Kun-Juan SHAO,Chun-Zhong LI,Tao HE. Visible-Light Photocatalytic Reduction of CO₂ by CoTe Prepared via a Template-Free Hydrothermal Method [J]. Acta Phys. -Chim. Sin., 2017, 33(9): 1884-1890.
[11]	Qi-Tang FAN,Jun-Fa ZHU. Controlling the Topology of Low-Dimensional Organic Nanostructures with Surface Templates [J]. Acta Phys. -Chim. Sin., 2017, 33(7): 1288-1296.
[12]	Jian-Ping QIU,Yi-Wen TONG,De-Ming ZHAO,Zhi-Qiao HE,Jian-Meng CHEN,Shuang SONG. Electrochemical Reduction of CO₂ to Methanol at TiO₂ Nanotube Electrodes [J]. Acta Phys. -Chim. Sin., 2017, 33(7): 1411-1420.
[13]	Xue-Hui HUANG,Xiao-Hui SHANG,Peng-Ju NIU. Surface Modification of SBA-15 and Its Effect on the Structure and Properties of Mesoporous La_0.8Sr_0.2CoO₃ [J]. Acta Phys. -Chim. Sin., 2017, 33(7): 1462-1473.
[14]	Xu ZHEN,Xue-Jing GUO. Synthesis and Lithium Storage Performance of Three-Dimensional Mesostructured ZnCo₂O₄ Cubes [J]. Acta Phys. -Chim. Sin., 2017, 33(4): 845-852.
[15]	Quan QUAN,Shun-Ji XIE,Ye WANG,Yi-Jun XU. Photoelectrochemical Reduction of CO₂ Over Graphene-Based Composites:Basic Principle, Recent Progress, and Future Perspective [J]. Acta Phys. -Chim. Sin., 2017, 33(12): 2404-2423.

Adsorption Capacity of Carbon Dioxide on Amine Modified Mesoporous Materials with Larger Pore Sizes

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Comments

Recommended 10