醇-可聚合表面活性剂混合胶束法合成微嵌段缔合聚合物及其流变性

doi:10.3866/PKU.WHXB201204231

Abstract

Abstract:

In this paper, mixed micelle composed of alcohol and polymerizable surfactant (surfmer) were constructed. The aggregated numbers of surfmer (hexadecyl trimethyl allylammonium chloride (C₁₆DMAAC)) in the mixed micelle were measured using a steady-state fluorescence quenching (SSFQ) technique. Using a mixed micellar method with adiabatic polymerization and post-hydrolyzation techniques, the high molecular weight (M_w) micro-block associative polymer of P(AM-NaAA-C₁₆DMAAC) was polymerized. Structures were characterized by Fourier transform-infrared (FT-IR) spectroscopy and ¹³C nuclear magnetic resonance (NMR) spectroscopy. Using rheological experiments, the effects of micro-block length and salt concentration of on the thickening and viscoelastic rheological properties of the polymers were studied. All experiments confirmed that the micro-block length could be adjusted using the mixed micellar method. Increases in the micro-block length were accompanied by decreases in the critical associative concentration (CAC). The viscosities and viscoelastic rheological properties increased to maximum then decreased steady with the length increasing, indicating that the length was at an optimum value.

Key words: Alcohols, Polymerizable surfactant, Associative polymer, Micro-block length, Mixed micelle, Rheology

MSC2000:

O647

LIU Jian-Xin, GUO Yong-Jun, ZHU Yang-Wen, YANG Hong-Ping, YANG Xue-Shan, ZHONG Jin-Hang, LI Hua-Bing, LUO Ping-Ya. Polymerization of Micro-Block Associative Polymer with Alcohol-Surfmer Mixed Micellar Method and Their Rheological Properties[J].Acta Phys. -Chim. Sin., 2012, 28(07): 1757-1763.

References

(1) Taylor, K. C.; Nasr-El-Din, H. A. J. Pet. Sci. Eng. 1998, 19, 265.doi: 10.1016/S0920-4105(97)00048-X
(2) Wever, D. A. Z.; Picchioni, F.; Broekhuis, A. A. Prog. Polym. Sci. 2011, 36, 1558. doi: 10.1016/j.progpolymsci.2011.05.006
(3) Volpert, E.; Selb, J.; Candau, F. Macromolecules 1996, 29,1452. doi: 10.1021/ma951178m
(4) Volpert, E.; Selb, J.; Candau, F. Polymer 1998, 39, 1025. doi: 10.1016/S0032-3861(97)00393-5
(5) Stähler, K.; Selb, J.; Candau, F. Langmuir 1999, 15, 7565. doi: 10.1021/la990431z
(6) Thunemann, A. F.; Kubowicz, S.; von Berlepsch, H.; Mohwald,H. Langmuir 2006, 22, 2506. doi: 10.1021/la0533720
(7) Gao, B. J.; Jiang, L. D.; Kong, D. L. Colloid Polym. Sci. 2007,285, 839. doi: 10.1007/s00396-006-1613-5
(8) Unsal, H.; Aydogan, N. Langmuir 2009, 25, 7884. doi: 10.1021/la900456t
(9) Biggs, S.; Selb, J.; Candau, F. Langmuir 1992, 8, 838. doi: 10.1021/la00039a018
(10) Bu, H.; Kjoniksen, A. L.; Elgsaeter, A.; Nystrom, B. Colloids Surf. A 2006, 278, 166. doi: 10.1016/j.colsurfa.2005.12.016
(11) Penott-Chang, E. K.; Gouveia, L.; Fernandez, I. J.; Muller, A. J.;Diaz-Barrios, A.; Saez, A. E. Colloids Surf. A 2007, 295, 99.doi: 10.1016/j.colsurfa.2006.08.038
(12) Talwar, S.; Scanu, L.; Raghavan, S. R.; Khan, S. A. Langmuir2008, 24, 7797. doi: 10.1021/la801030n
(13) Chen, H.; Li, E. X.; Ye, Z. B.; Han, L. J.; Luo, P. Y. Acta Phys. -Chim. Sin. 2011, 27, 671. [陈洪, 李二晓, 叶仲斌,韩利娟, 罗平亚. 物理化学学报, 2011, 27, 671.] doi: 10.3866//PKU.WHXB20110306
(14) Summers, M.; Eastoe, J. Adv. Colloid Interface Sci. 2003,100-102, 137.
(15) Guyot, A. Adv. Colloid Interface Sci. 2004, 108, 3. doi: 10.1016/j.cis.2003.10.009
(16) Tajima, K.; Aida, T. Chem. Commun. 2000, 2399.
(17) Candau, F.; Regalado, E. J.; Selb, J. Macromolecules 1998, 31,5550. doi: 10.1021/ma9802982
(18) Attwood, D.; Mosquera, V.; Rodriguez, J.; Garcia, M.; Suarez,M. J. Colloid & Polymer Science 1994, 272, 584. doi: 10.1007/BF00653225
(19) Zhang, X. F.;Wu,W. H. Chin. Chem. Lett. 2009, 20, 1361. doi: 10.1016/j.cclet.2009.06.011
(20) Lianos, P.; Zana, R. Chem. Phys. Lett. 1980, 76, 62. doi: 10.1016/0009-2614(80)80605-1
(21) Zana, R.; Yiv, S.; Strazielle, C.; Lianos, P. J. Colloid Interface Sci. 1981, 80, 208. doi: 10.1016/0021-9797(81)90177-6
(22) Zhou, Y. X.; Guo, Y. J.; Luo, P. Y. J. Southwest Pet. Inst. 2004,26, 62. [周云霞, 郭拥军, 罗平亚. 西南石油学院学报, 2004,26, 62.]
(23) Zhang,W. C.; Li, G. Z.; Shen, Q.; Lu, Y. J. Acta Chim. Sin.2000, 58, 374. [张为灿, 李干佐, 沈强, 卢拥军. 化学学报,2000, 58, 374.]
(24) Abdurrahmanoglu, S.; Can, V.; Okay, O. Polymer 2009, 50,5449. doi: 10.1016/j.polymer.2009.09.042
(25) Candau, F.; Selb, J. Adv. Colloid Interface Sci. 1999, 79, 149.doi: 10.1016/S0001-8686(98)00077-3
(26) Chassenieux, C.; Nicolai, T.; Benyahia, L. Curr. Opin. Colloid Interface Sci. 2011, 16, 18. doi: 10.1016/j.cocis.2010.07.007
(27) Yu, Y. M.;Wang, Z. H.; Gao, B. J.;Wang, R. X. Acta Phys. -Chim. Sin. 2006, 22, 496. [于亚明, 王中华, 高保娇,王蕊欣. 物理化学学报, 2006, 22, 496.] doi: 10.3866/PKU.WHXB20060421
(28) Kujawa, P.; Audibert-Hayet, A.; Selb, J.; Candau, F.Macromolecules 2006, 39, 384. doi: 10.1021/ma051312v
(29) Regalado, E. J.; Selb, J.; Candau, F. Macromolecules 1999, 32,8580. doi: 10.1021/ma990999e

[1]	Bo Fang,Ligang Feng. PtCo-NC Catalyst Derived from the Pyrolysis of Pt-Incorporated ZIF-67 for Alcohols Fuel Electrooxidation [J]. Acta Physico-Chimica Sinica, 2020, 36(7): 1905023-0.
[2]	Zhaobi Xing,Zhijun Guo,Yuwei Zhang,Junling Liu,Yujie Wang,Guangyue Bai. Regulation of SDS on the Surface Charge Density of SB3-12 Micelles and Its Effect on Drug Dissolution [J]. Acta Physico-Chimica Sinica, 2020, 36(6): 1906006-0.
[3]	Zhihua ZHOU,Shumei XIA,Liangnian HE. Green Catalysis for Three-Component Reaction of Carbon Dioxide, Propargylic Alcohols and Nucleophiles [J]. Acta Physico-Chimica Sinica, 2018, 34(8): 838-844.
[4]	Pei-Yi LIAO,Chen ZHANG,Li-Jun ZHANG,Yan-Zhang YANG,Liang-Shu ZHONG,Xiao-Ya GUO,Hui WANG,Yu-Han SUN. Influences of Cu Content on the Cu/Co/Mn/Al Catalysts Derived from Hydrotalcite-Like Precursors for Higher Alcohols Synthesis via Syngas [J]. Acta Phys. -Chim. Sin., 2017, 33(8): 1672-1680.
[5]	Xiao-Hong ZHANG,Hong-Yan XU,Ling-Ling GE,Rong GUO. Mixed Micelle of Surface Active Ionic Liquid Lauryl Isoquinolinium Bromide and Nonionic Surfactant Triton X-100 in Aqueous Solutions [J]. Acta Phys. -Chim. Sin., 2016, 32(1): 356-364.
[6]	WANG Ji-Qian, SUN Ying-Jie, DAI Jing-Ru, ZHAO Yu-Rong, CAO Mei-Wen, WANG Dong, XU Hai. Effects of Alkyl Chain Length and Peptide Charge Distribution on Self-Assembly and Hydrogelation of Lipopeptide Amphiphiles [J]. Acta Phys. -Chim. Sin., 2015, 31(7): 1365-1373.
[7]	Yi-Xiu. HAN,Hong. ZHOU,Yong-Qiang. WEI,Yong-Jun. MEI,Hang. WANG. Effect of TBAB/KCl on Constructing Anionic Wormlike Micelles [J]. Acta Phys. -Chim. Sin., 2015, 31(11): 2124-2130.
[8]	DONG Wen-Da, ZHU He-Jun, DING Yun-Jie, PEI Yan-Peng, DU Hong, WANG Tao. Effect of Trace Amounts of Li Doping on Performance of Co/AC Catalysts for Syntheses of Mixed Linear α-Alcohols [J]. Acta Phys. -Chim. Sin., 2014, 30(9): 1745-1751.
[9]	CAO Xu-Long, LI Jing, YANG Yong, ZHANG Ji-Chao, ZHANG Lei, ZHANG Lu, ZHAO Sui. Effects of Surfactants on Interfacial Shear Rheological Properties of Polymers for Enhanced Oil Recovery [J]. Acta Phys. -Chim. Sin., 2014, 30(5): 908-916.
[10]	ZHAI Xue-Ru, LIU Teng, XU Gui-Ying, TAN Guo-Rong, Lü Xin, ZHANG Jian. Aggregation Behavior of Branched Block Polyethers at Interface and Their Demulsification for Crude Oil Emulsion [J]. Acta Phys. -Chim. Sin., 2013, 29(06): 1253-1259.
[11]	YAO Fang-Fang, WU Bao-Shan, ZHOU Li-Ping, GAO Jun-Hu, LI Ying, LI Yong-Wang. Effect of Alcohol Addition on Fischer-Tropsch Synthesis over Cobalt-Based Catalysts [J]. Acta Phys. -Chim. Sin., 2013, 29(05): 1063-1072.
[12]	LIU Jian-Guo, DING Ming-Yue, WANG Tie-Jun, MA Long-Long. Structure and Performance of Cu-Fe Bimodal Support for Higher Alcohol Syntheses [J]. Acta Phys. -Chim. Sin., 2012, 28(08): 1964-1970.
[13]	MEI Yong-Jun, HAN Yi-Xiu, ZHOU Hong, YAO Lin, JIANG Bo. Synergism between Hydrophobically Modified Polyacrylic Acid and Wormlike Micelles [J]. Acta Phys. -Chim. Sin., 2012, 28(07): 1751-1756.
[14]	GUO Hai-Jun, XIONG Lian, LUO Cai-Rong, DING Fei, CHEN Xin-De, CHEN Yong. Effect of Fe/Co Mass Ratio on Catalytic Performances of Cu-Fe-Co Based Catalysts for Mixed Alcohols Synthesis [J]. Acta Phys. -Chim. Sin., 2011, 27(11): 2632-2638.
[15]	MAO Dong-Sen, GUO Qiang-Sheng, YU Jun, HAN Lu-Peng, LU Guan-Zhong. Effect of Cerium Addition on the Catalytic Performance of Cu-Fe/SiO₂ for the Synthesis of Lower Alcohols from Syngas [J]. Acta Phys. -Chim. Sin., 2011, 27(11): 2639-2645.

Polymerization of Micro-Block Associative Polymer with Alcohol-Surfmer Mixed Micellar Method and Their Rheological Properties

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Comments

Recommended 0