疏水缔合聚丙烯酸与蠕虫状胶束的协同作用

doi:10.3866/PKU.WHXB201204233

Abstract

Abstract:

The synergism between wormlike micelles formed from sodium oleate (NaOA) and hydrophobically modified polyacrylic acid (HMPA) was investigated according to their macroscopic performances and mesoscopic scales, using a combination of viscosity/rheology measurements and dissipative particle dynamics (DPD) molecular simulations. The rheology of NaOA wormlike micelles changed significantly following the addition of a small amount of HMPA, which verified the synergistic effect between them. A peak in the apparent viscosity was observed following an increase in the concentration of HMPA, suggesting that the synergistic effect was restricted by the composition of the mixture. A DPD simulation also confirmed that the solution composition had an influence on the root mean square (RMS) end-to-end distances of HMPA, with the observed value fluctuating according to NaOA and HMPA concentrations. The micellar morphology affected the RMS end-to-end distances of HMPA and the presence of NaOA micelles exerted a significant impact on the extension of HMPA at high HMPA concentrations. A proposed synergistic mechanism has been presented according to the experimental and simulation results.

Key words: Hydrophobically modified polyacrylic acid, Wormlike micelle, Rheology, Apparent viscosity, Dissipative particle dynamics molecular simulation, Root mean square end-to-end distance

MSC2000:

O641

MEI Yong-Jun, HAN Yi-Xiu, ZHOU Hong, YAO Lin, JIANG Bo. Synergism between Hydrophobically Modified Polyacrylic Acid and Wormlike Micelles[J].Acta Phys. -Chim. Sin., 2012, 28(07): 1751-1756.

References

(1) Bjerke, A. E.; Griffiths, P. R.; Theiss,W. Anal. Chem. 1999, 71,1967. doi: 10.1021/ac981093u
(2) Camara, G. A.; Gomes, J. F.; Bergamaski, K.; Teixeira-Neto, E.;Nart, F. C. J. Electroanal. Chem. 2008, 617, 171. doi: 10.1016/j.jelechem.2008.02.005
(3) Sato, T.; Okaya, K.; Yano, H.;Wanatabe, M.; Uchida, H. ACS Catal. 2012, 2, 450. doi: 10.1021/cs200550t
(4) Zhang, P.;Wang, L. F.; Xu, J. C. Spectroscopy and Spectral Analysis 2003, 23, 46. [张平, 王乐夫, 徐建昌. 光谱学与光谱分析, 2003, 23, 46.]
(5) Lin,W. F.; Iwasita, T.; Vielstich,W. J. Phys. Chem. B 1999, 103,3250. doi: 10.1021/jp984491+
(6) Harstein, A.; Kirtley, J. R.; Tsang, J. C. Phys. Rev. Lett. 1980,45, 201. doi: 10.1103/PhysRevLett.45.201
(7) Osawa, M. Bull. Chem. Soc. Jpn. 1997, 70, 2861. doi: 10.1246/bcsj.70.2861
(8) Fano, U. Phys. Rev. 1961, 6, 1866.
(9) Lu, G. Q.; Sun, S. G.; Cai, L. R.; Chen, S. P.; Tian, Z.W.Langmuir 2000, 16, 778. doi: 10.1021/la990282k
(10) Miki, A.; Ye, S.; Osawa, M. Chem. Commun. 2002, 1500.
(11) Chen, Y. X.; Miki, A.; Ye, S.; Sakai, H.; Osawa, M. J. Am. Chem. Soc. 2003, 125, 3680. doi: 10.1021/ja029044t
(12) Huo, S. J.; Xue, X. K.; Yan, Y. G.; Li, Q. X.; Ma, M.; Cai,W.B.; Xu, Q. J.; Osawa, M. J. Phys. Chem. B 2006, 110, 4162. doi: 10.1021/jp0566966
(13) Huo, S. J.; Xue, X. K.; Li, Q. X.; Xu, S. F.; Cai,W. B. J. Phys. Chem. B 2006, 110, 25721. doi: 10.1021/jp064036a
(14) Cai, L. R.; Sun, S. G.; Xia, S. Q.; Chen, F.; Zheng, M. S.; Chen,S. P.; Lu, G. Q. Acta Phys. -Chim. Sin. 1999, 15, 1023. [蔡丽蓉, 孙世刚, 夏盛清, 陈芳, 郑明森, 陈声培, 卢国强. 物理化学学报, 1999, 15, 1023.] doi: 10.3866/PKU.WHXB19991113
(15) Gong, H.; Sun, S. G.; Li, J. T.; Chen, Y. J.; Chen, S. P.Electrochim. Acta 2003, 48, 2933. doi: 10.1016/S0013-4686(03)00358-X
(16) Chen, Q. S.; Sun, S. G.; Yan, J.W.; Li, J. T.; Zhou, Z. Y.Langmuir 2006, 22, 10575. doi: 10.1021/la0615037
(17) Ortiz, R.; Cuesta, A.; Marquez, O. P.; Gutierrez, C.J. Electroanal. Chem. 1999, 465, 234. doi: 10.1016/S0022-0728(99)00099-6
(18) Orozco, G.; Gutierrez, C. J. Electroanal. Chem. 2000, 484, 64.doi: 10.1016/S0022-0728(00)00062-0
(19) Lin,W. G.; Sun, S. G.; Zhou, Z. Y.; Chen, S. P.;Wang, H. C.J. Phys. Chem. B 2002, 106, 11778. doi: 10.1021/jp025917u
(20) Chen, Z.; Sun, S. G.; Ding, N.; Zhou, Z. Y. Chin. Sci. Bull.2001, 46, 1439. doi: 10.1007/BF03187026
(21) Chen, Q. S.; Sun, S. G.; Zhou, Z. Y.; Chen, Y. X.; Deng, S. B.Phys. Chem. Chem. Phys. 2008, 10, 3645.
(22) Gong, H.; Sun, S. G.; Chen, Y. J.; Chen, S. P. J. Phys. Chem. B2004, 108, 11575. doi: 10.1021/jp0375822
(23) Chen, Y. J.; Sun, S. G.; Chen, S. P.; Li, J. T.; Gong, H. Langmuir2004, 20, 9920. doi: 10.1021/la048484q
(24) Feltham, A. M.; Spiro, M. Chem. Rev. 1971, 71, 177. doi: 10.1021/cr60270a002
(25) Su, Z. F.; Sun, S. G.;Wu, C. X.; Cai, Z. P. J. Chem. Phys. 2008,129, 044707. doi: 10.1063/1.2953441
(26) Krauth, O.; Fahsold, G.; Pucci, A. J. Mol. Struct. 1999, 482,237. doi: 10.1016/S0022-2860(98)00851-5
(27) Krauth, O.; Fahsold, G.; Pucci, A. J. Chem. Phys. 1999, 110,3113. doi: 10.1063/1.477907
(28) Wu, C. X.; Lin, H.; Chen, Y. J.; Li,W. X.; Sun, S. G. J. Chem. Phys. 2004, 121, 1553. doi: 10.1063/1.1763135
(29) Wu, C. X.; Zhao,W.; Iwamoto, M.; Ouyang, Z. C. J. Chem. Phys. 2000, 112, 10548. doi: 10.1063/1.481688

[1]	Tongqing Liu, Fangfang Xue, Ping Yi, Zhiyu Xia, Jinfeng Dong, Xuefeng Li. Structure–Property Relationship of Light-Responsive Wormlike Micelles Using Methoxycinnamate Derivatives as Light-Switchable Molecules [J]. Acta Physico-Chimica Sinica, 2020, 36(10): 1910004-0.
[2]	Yimin Hu, Jie Han, Rong Guo. Wormlike Micelle to Gel Transition Induced by Brij 30 in Ionic Liquid-Type Surfactant Aqueous Solution [J]. Acta Physico-Chimica Sinica, 2020, 36(10): 1909049-0.
[3]	Hengchang LIU,Yujun FENG. CO₂-Induced Interaction between a Pentablock Nonionic Copolymer and an Anionic Fluorocarbon Surfactant [J]. Acta Phys. -Chim. Sin., 2019, 35(4): 408-414.
[4]	Ping-Ping ZHOU,Xi XI,Bing-Lei SONG,Xiao-Mei PEI,Zheng-Gang CUI. Rheological Behavior of Trimeric Anionic Surfactant/Cationic Additive Mixed Systems [J]. Acta Phys. -Chim. Sin., 2016, 32(9): 2309-2317.
[5]	WANG Ji-Qian, SUN Ying-Jie, DAI Jing-Ru, ZHAO Yu-Rong, CAO Mei-Wen, WANG Dong, XU Hai. Effects of Alkyl Chain Length and Peptide Charge Distribution on Self-Assembly and Hydrogelation of Lipopeptide Amphiphiles [J]. Acta Phys. -Chim. Sin., 2015, 31(7): 1365-1373.
[6]	Yi-Xiu. HAN,Hong. ZHOU,Yong-Qiang. WEI,Yong-Jun. MEI,Hang. WANG. Effect of TBAB/KCl on Constructing Anionic Wormlike Micelles [J]. Acta Phys. -Chim. Sin., 2015, 31(11): 2124-2130.
[7]	CAO Xu-Long, LI Jing, YANG Yong, ZHANG Ji-Chao, ZHANG Lei, ZHANG Lu, ZHAO Sui. Effects of Surfactants on Interfacial Shear Rheological Properties of Polymers for Enhanced Oil Recovery [J]. Acta Phys. -Chim. Sin., 2014, 30(5): 908-916.
[8]	XIE Dan-Hua, ZHAO Jian-Xi, LIU Lin, YOU Yi, WEI Xi-Lian. A Highly Viscoelastic Anionic Wormlike Micellar System [J]. Acta Phys. -Chim. Sin., 2013, 29(07): 1534-1540.
[9]	ZHAI Xue-Ru, LIU Teng, XU Gui-Ying, TAN Guo-Rong, Lü Xin, ZHANG Jian. Aggregation Behavior of Branched Block Polyethers at Interface and Their Demulsification for Crude Oil Emulsion [J]. Acta Phys. -Chim. Sin., 2013, 29(06): 1253-1259.
[10]	LIU Jian-Xin, GUO Yong-Jun, ZHU Yang-Wen, YANG Hong-Ping, YANG Xue-Shan, ZHONG Jin-Hang, LI Hua-Bing, LUO Ping-Ya. Polymerization of Micro-Block Associative Polymer with Alcohol-Surfmer Mixed Micellar Method and Their Rheological Properties [J]. Acta Phys. -Chim. Sin., 2012, 28(07): 1757-1763.
[11]	PEI Xiao-Mei, ZHAO Jian-Xi, WEI Xi-Lian. Effect of Sodium Salicylate on the Formation and Properties of Wormlike Micelles in Aqueous Cationic Gemini Surfactant Solutions [J]. Acta Phys. -Chim. Sin., 2011, 27(04): 913-917.
[12]	ZONG Hua, WANG Lei, FANG Hong-Bo, MAO Lei-Ting, WANG Yu-Hui, ZHANG Lu, ZHAO Sui, YU Jia-Yong. Effect of Hydrophobically Modified Polyacrylamide on Interfacial Dilational Rheological Properties of Crude Oil Components [J]. Acta Phys. -Chim. Sin., 2010, 26(11): 2982-2988.
[13]	ZHU Yan-Yan; XU Gui-Ying. Investigation of Macromolecule/Surfactant Interaction by Interfacial Dilational Rheology Method [J]. Acta Phys. -Chim. Sin., 2009, 25(01): 191-200.
[14]	WANG Hong-Xia;ZHANG Gao-Yong;LIU Dian-Sheng;ZHANG Xin-Wei;XIAO Yong-Hong. Small Amplitude Oscillation Frequency Sweep of Lamellar Liquid Crystal [J]. Acta Phys. -Chim. Sin., 2005, 21(12): 1411-1414.
[15]	XU Hua; XU Yao; LI Zhi-Hong. Study of the Microstructure of TEOS-MTES Based Sol by SAXS [J]. Acta Phys. -Chim. Sin., 2005, 21(03): 300-305.

Synergism between Hydrophobically Modified Polyacrylic Acid and Wormlike Micelles

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Comments

Recommended 0