高盐油藏下两性/阴离子表面活性剂协同获得油水超低界面张力

doi:10.3866/PKU.WHXB201206291

Abstract

Abstract:

The present work investigates the use of synergistic interactions between zwitterionic and anionic surfactants to obtain ultra-low interfacial tension (IFT) in a high salinity reservoir. Zwitterionic surfactant N-hexadecyl-N,N-dimethyl-3-ammonio-1-propanesulfonate was found to be compatible with simulated high salinity water, reducing crude oil/water interfacial tension to a magnitude of 10^-2 mN·m^-1 in a surfactant concentration range of 0.07%-0.39% (mass fraction), whereas ultra-low IFT was obtained by adding anionic surfactant sodium dodecyl sulfate. Furthermore, the effects of total surfactant concentration, metal ion concentration, and molar ratio on the dynamic interfacial tension of zwitterionic/anionic surfactant mixtures were studied. Results showed that 10^-5 mN·m^-1 magnitude ultra-low IFT was obtained over a wide range of surfactant concentrations from as low as 0.04% and up to 0.37% in high salinity water. The synergistic mechanism of ultra-low IFT formed in zwitterionic/anionic surfactant systems was further analyzed.

Key words: Zwitterionic surfactant, Anionic surfactant, Synergistic effect, Ultra-low interfacial tension, Salt tolerance

MSC2000:

O647

WANG Xian-Zhong, KANG Wan-Li, MENG Xiang-Can, FAN Hai-Ming, XU Hai, HUANG Jing-Wei, FU Jian-Bin, ZHANG Yi-Nuo. Ultra-Low Interfacial Tension in High Salinity Reservoir Driven by Synergistic Interaction of Zwitterionic and Anionic Surfactants[J].Acta Phys. -Chim. Sin., 2012, 28(10): 2285-2290.

References

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Ultra-Low Interfacial Tension in High Salinity Reservoir Driven by Synergistic Interaction of Zwitterionic and Anionic Surfactants

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