高盐油藏下两性/阴离子表面活性剂协同获得油水超低界面张力

doi:10.3866/PKU.WHXB201206291

Abstract

Abstract:

The present work investigates the use of synergistic interactions between zwitterionic and anionic surfactants to obtain ultra-low interfacial tension (IFT) in a high salinity reservoir. Zwitterionic surfactant N-hexadecyl-N,N-dimethyl-3-ammonio-1-propanesulfonate was found to be compatible with simulated high salinity water, reducing crude oil/water interfacial tension to a magnitude of 10^-2 mN·m^-1 in a surfactant concentration range of 0.07%-0.39% (mass fraction), whereas ultra-low IFT was obtained by adding anionic surfactant sodium dodecyl sulfate. Furthermore, the effects of total surfactant concentration, metal ion concentration, and molar ratio on the dynamic interfacial tension of zwitterionic/anionic surfactant mixtures were studied. Results showed that 10^-5 mN·m^-1 magnitude ultra-low IFT was obtained over a wide range of surfactant concentrations from as low as 0.04% and up to 0.37% in high salinity water. The synergistic mechanism of ultra-low IFT formed in zwitterionic/anionic surfactant systems was further analyzed.

Key words: Zwitterionic surfactant, Anionic surfactant, Synergistic effect, Ultra-low interfacial tension, Salt tolerance

MSC2000:

O647

WANG Xian-Zhong, KANG Wan-Li, MENG Xiang-Can, FAN Hai-Ming, XU Hai, HUANG Jing-Wei, FU Jian-Bin, ZHANG Yi-Nuo. Ultra-Low Interfacial Tension in High Salinity Reservoir Driven by Synergistic Interaction of Zwitterionic and Anionic Surfactants[J].Acta Phys. -Chim. Sin., 2012, 28(10): 2285-2290.

References

(1) Song,W. D.; Fang, T.;Wang, Q. K.; Zhou, Y. B. Energy Technology and Economics 2010, 22, 18. [宋卫东, 方彤,王乾坤, 周原冰. 能源技术经济, 2010, 22, 18.]
(2) Zhao, F. L. Principles of Enhanced Oil Recovery; ChinaUniversity of Petroleum Press: Dongying, 2006; pp 1-2.[赵福麟. EOR 原理. 东营: 石油大学出版社, 2006: 1-2.]
(3) Krumrine, P. H.; Falcone, J. S., Jr. Surfactant, Polymer, and Alkali Interactions in Chemical Flooding Processes, paper SPE11778 presented at the International Symposium on Oilfield andGeothermal Chemistry, Denver, Texas, June 1-3, 1983.
(4) Delshad, M.; Han,W.; Pope, G. A.; Sepehrnoori, K.;Wu,W.;Yang, R.; Zhao, L. Alkaline/Surfactant/Polymer Flood Predictions for the Karamay Oil Field, paper SPE 39610presented at the SPE/DOE Symposium on Improved OilRecovery, Tulsa, Oklahoma, April 19-22, 1998.
(5) Qu, Z. J.; Zhang, Y. G.; Zhang, X. S.; Dai, J. L. A Successful ASP Flooding Pilot in Gudong Oil Field, paper SPE 39613presented at the SPE/DOE Symposium on Improved OilRecovery, Tulsa, Oklahoma, April 19-22, 1998.
(6) Wang, D. M.; Cheng, J. C.;Wu, J. Z.; Yang, Z. Y.; Yao, Y. M.;Li, H. F. Summary of ASP Pilots in Daqing Oil Field, paper SPE57288 presented at the SPE Asia Pacific Improved Oil RecoveryConference, Kuala Lumpur, Malaysia, October 25-26, 1999.
(7) Green, D.W.;Willhite, G. P. Enhanced Oil Recovery; Henry, L.Ed., Doherty Memorial Fund of AIME, Society of PetroleumEngineers: Richardson, 1998; pp 12-35.
(8) Kang,W. L.; Liu, Y. J. China Surfactant Detergent & Cosmetics2000, 4, 30. [康万利, 刘永建. 日用化学工业, 2000, 4, 30.]
(9) Zhang, L.; Luo, L.; Zhao, S.; Xu, Z. C.; An, J. Y.; Yu, J. Y.J. Petro. Sci. Eng. 2004, 41, 189. doi: 10.1016/S0920-4105(03)00153-0
(10) Chu, Y. P.; Gong, Y.; Tan, X. L.; Zhang, L.; Zhao, S.; An, J. Y.;Yu, J. Y. J. Colloid Interface Sci. 2004, 276, 182. doi: 10.1016/j.jcis.2004.03.007
(11) Zhang, S.; Xu, Y.; Qiao,W.; Li, Z. Fuel 2004, 83, 2059. doi: 10.1016/j.fuel.2004.04.001
(12) Guo, D. H.; Xin, H. C.; Cui, X. D.; Xie, H. Z. Petroleum Processing and Petrochemicals 2005, 12, 41. [郭东红, 辛浩川, 崔晓东, 谢慧专. 石油炼制与化工, 2005, 12, 41.]
(13) Zhao, Z. K.; Li, Z. S.; Zhao, S.; Qiao,W. H.; Cheng, L. B.Colloid Surf. A: Physicochem. Eng. Asp. 2005, 259, 71. doi: 10.1016/j.colsurfa.2005.02.012
(14) Gong, H. J.; Xia, X.; Xu, G.;Wang, Y. J. Colloids Surf. A: Physicochem. Eng. Asp. 2008, 317, 522. doi: 10.1016/j.colsurfa.2007.11.034
(15) Han, X.; Cheng, X. H.;Wang, J.; Huang, J. B. Acta Phys. -Chim. Sin. 2012, 28, 146. [韩霞, 程新皓, 王江, 黄建滨. 物理化学学报, 2012, 28, 146.] doi: 10.3866/PKU.WHXB201228146
(16) Hou, J. R.; Liu, Z. C.; Yue, X. A. Petroleum Geology & Oilfield Development in Daqing 2006, 25, 82. [侯吉瑞, 刘中春, 岳湘安. 大庆石油地质与开发, 2006, 25, 82.]
(17) Yuan, X. Q.; Li, B. G.; Zhao, J. Y. Oilfield Chemistry 2008, 25,170. [袁新强, 李佰广, 赵劲毅. 油田化学, 2008, 25, 170.]
(18) Sheng, D. Q. Well Testing and Production Technology 1995, 16,60. [绳德强. 试采技术, 1995, 16, 60.]
(19) Chen, S. Y.; Liu, A. F.; Sun, X. N.; Liu, M. T.; Lin, T. Petroleum Geology & Oilfield Development in Daqing 2006, 25, 97. [陈仕宇, 刘安芳, 孙雪娜, 刘明涛, 林涛. 大庆石油地质与开发,2006, 25, 97.]
(20) Zaitoun, A.; Fonseca, C.; Berger, P.; Baizin, B.; Monin, N. New Surfactant for Chemical Flood in High-Salinity Reservoir, paperSPE 80237 presented at the SPE International Symposium onOilfield Chemistry, Houston, Texas, February 5-7, 2003.
(21) Chen, H.; Han, L.; Luo, P.; Ye, Z. Journal of Colloid and Interface Science 2005, 285, 872. doi: 10.1016/j.jcis.2004.11.066
(22) Chen, H.; Han, L.; Luo, P.; Ye, Z. Surface Science 2005, 552,L53.
(23) Wu,W. X.; Zhang,W.; Liu, C. D. Oilfield Chemistry 2007, 24,60. [吴文祥, 张武, 刘春德. 油田化学, 2007, 24, 60.]
(24) Wang, D. M.; Liu, C. D.;Wu,W. X. Development of an Ultra-Low Interfacial Tension Surfactant in a System with No-alkali for Chemical Flooding, paper SPE 109017 presentedat the SPE/DOE Improved Oil Recovery, Tulsa, Oklahoma,April 19-23, 2008.
(25) Wu,W. X.; Yin, Q. G.; Liu, C. D. Petroleum Geology and Recovery Efficiency 2009, 16, 67. [吴文祥, 殷庆国, 刘春德.油气地质与采收率, 2009, 16, 67.]
(26) Zhao, G. X.; Zhu, B. Y. Principles of Surfactant Action; Chinalight Industry Press: Beijing, 2003; pp 356-382. [赵国玺, 朱瑶. 表面活性剂作用原理. 北京: 中国轻工业出版社, 2003:356-382.]
(27) Rubin, E.; Radke, C. J. Chemical Engineering Science 1980, 5,1129.

[1]	Qianqian WANG, Dajun LIU, Xingquan HE. Metal-Organic Framework-Derived Fe-N-C Nanohybrids as Highly-Efficient Oxygen Reduction Catalysts [J]. Acta Physico-Chimica Sinica, 2019, 35(7): 740-748.
[2]	Mao-Zhang TIAN,Fan ZHANG,Cheng MA,De-Sheng MA,Ling-Xiang JIANG,Rong-Rong XUE,Ka-Er-Dun LIU,Jian-Bin HUANG. Viscosity Reduction of Heavy Oils of Different Viscosities Based on General Cationic/Anionic Surfactant Systems [J]. Acta Phys. -Chim. Sin., 2017, 33(8): 1665-1671.
[3]	Zhou-Sheng MO,Yu-Cai QIN,Xiao-Tong ZHANG,Lin-Hai DUAN,Li-Juan SONG. Influencing Mechanism of Cyclohexene on Thiophene Adsorption over CuY Zeolites [J]. Acta Phys. -Chim. Sin., 2017, 33(6): 1236-1241.
[4]	Ping-Ping ZHOU,Xi XI,Bing-Lei SONG,Xiao-Mei PEI,Zheng-Gang CUI. Rheological Behavior of Trimeric Anionic Surfactant/Cationic Additive Mixed Systems [J]. Acta Phys. -Chim. Sin., 2016, 32(9): 2309-2317.
[5]	Zi-Yu LIU,Qi LIAO,Zhi-Qiang JIN,Lei ZHANG,Lu ZHANG. Effect of Electrolytes on the Interfacial Behavior of Nonionic-Anionic Surfactant Solutions Using Molecular Dynamics Simulations [J]. Acta Phys. -Chim. Sin., 2016, 32(5): 1168-1174.
[6]	Wei TANG,Jing WANG. Enhanced Gas Sensing Mechanisms of Metal Oxide Heterojunction Gas Sensors [J]. Acta Phys. -Chim. Sin., 2016, 32(5): 1087-1104.
[7]	Li-Fang HU,Jie HE,Yuan LIU,Yun-Lei ZHAO,Kai CHEN. Structural Features and Photocatalytic Performance of TiO₂-HNbMoO₆ Composite [J]. Acta Phys. -Chim. Sin., 2016, 32(3): 737-744.
[8]	Wen-Jing. DONG,Jian-Xi. ZHAO. Self-Assembly of Cationic/Anionic Surfactants with Highly Dissymmetric Lengths of Alkyl Tails [J]. Acta Phys. -Chim. Sin., 2015, 31(8): 1535-1540.
[9]	WANG Wen-Xuan, DENG Shao-Xin, SHI Cheng-Xiang, SUN Ping-Chuan, CHEN Tie-Hong. Synthesis of Mesoporous Silica Using Anionic Surfactant/Cationic Polyamine as a Template [J]. Acta Phys. -Chim. Sin., 2015, 31(4): 707-714.
[10]	YUAN Fu-Qing, LIU Dan-Dan, GUO Lan-Lei, ZHU Yang-Wen, XU Zhi-Cheng, HUANG Jian-Bin, ZHANG Lei, ZHANG Lu. Effect of Branched Cationic and Betaine Surfactants on the Wettability of a Poly(tetrafluoroethylene) Surface [J]. Acta Phys. -Chim. Sin., 2015, 31(4): 715-721.
[11]	Yi-Xiu. HAN,Hong. ZHOU,Yong-Qiang. WEI,Yong-Jun. MEI,Hang. WANG. Effect of TBAB/KCl on Constructing Anionic Wormlike Micelles [J]. Acta Phys. -Chim. Sin., 2015, 31(11): 2124-2130.
[12]	Song-Shuang. HU,Lei. ZHANG,Zhi-Cheng. XU,Qing-Tao. GONG,Zhi-Qiang. JIN,Lu. ZHANG,Sui. ZHAO. Effect of Benzyl-Substituted Alkyl Betaine on the Wettability of a Poly(tetrafluoroethylene) Surface [J]. Acta Phys. -Chim. Sin., 2015, 31(10): 1924-1931.
[13]	CAO Xu-Long, ZHAO Hai-Na, MA Cheng, MA Bao-Dong, ZHANG Ji-Chao, YAN Lan, HUANG Jian-Bin. Behavior of Emulsification and Thickening of Crude Oil in Mixed Cationic and Anionic Surfactant Systems [J]. Acta Phys. -Chim. Sin., 2014, 30(7): 1297-1302.
[14]	CHENG Xin-Hao, ZHAO Ou-Di, ZHAO Hai-Na, HUANG Jian-Bin. Surface Properties in the Mixed Systems of Dodecylammonium Chloride and Sodium Alcohol Ether Sulphate [J]. Acta Phys. -Chim. Sin., 2014, 30(5): 917-922.
[15]	ZHANG Chen, ZHAO Jing-Mao. Synergistic Inhibition Effect of Imidazoline Ammonium Salt and Sodium Dodecyl Sulfate in CO₂ System [J]. Acta Phys. -Chim. Sin., 2014, 30(4): 677-685.

Ultra-Low Interfacial Tension in High Salinity Reservoir Driven by Synergistic Interaction of Zwitterionic and Anionic Surfactants

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Comments

Recommended 10