还原剂对多孔阳极氧化铝纳米孔道结构的影响

doi:10.3866/PKU.WHXB201208151

Abstract

Abstract:

In recent years, attention has been focused on adjustment and control of the nanostructures of porous anodic alumina (PAA) and porous anodic TiO₂ nanotubes (PATNT). Because the formation mechanism of PAA and PATNT is still unclear, it is difficult to adjust the nanostructures of PAA and PATNT. To validate the novel viewpoint of the nanopore resulting from an oxygen bubble mold, an innovative chemical approach was used to adjust the PAA nanostructures. One successful approach is to use a reducer to absorb the oxygen bubbles in the nanopores. A novel anodic alumina film was obtained in a mixed solution of the reducer and oxalic acid. The influence of the reducer on the PAA nanostructures which formed in H₃PO₄ solution was investigated in detail. The experimental results showed that the regularity and the diameters of the nanopores in the PAA decreased as the reducer content increased. The differences in the voltage-time curves between electrolytes with and without the reducer were analyzed quantitatively. The results showed that the conductivity of the anodic oxide film that formed in the electrolyte with the reducer was better than that in the electrolyte without the reducer. When aluminum anodizes in a sealed case, oxygen bubbles are easily absorbed by the reducer, the oxygen bubble mold effect disappears, and a compact alumina film is obtained. Overall, these results clearly demonstrate that nanopores result from the oxygen bubble mold effect.

Key words: Nanoporous material, Anodization, Electrolyte, Reducer, Formation mechanism

MSC2000:

O646

ZHU Xu-Fei, HAN Hua, MA Hong-Tu, LU Chao, QI Wei-Xing, XU Chen. Influence of Reducer on the Nanopore Structure of Porous Anodic Alumina[J].Acta Phys. -Chim. Sin., 2012, 28(11): 2648-2658.

References

(1) Zhang, H.; Hu, Y. J.;Wu, P.; Zhang, H.; Cai, C. X. Acta Phys. -Chim. Sin. 2012, 28, 1545. [张华, 胡耀娟, 吴萍,张卉, 蔡称心. 物理化学学报, 2012, 28, 1545.] doi: 10.3866/PKU.WHXB201203026
(2) Zhang,W. G.; Shang, Y. P.; Liu, L. N.; Yao, S.W.;Wang, H. Z.Acta Phys. -Chim. Sin. 2011, 27, 900. [张卫国, 尚云鹏, 刘丽娜, 姚素薇, 王宏智. 物理化学学报, 2011, 27, 900.] doi: 10.3866/PKU.WHXB20110344
(3) Guo, Y. Y.;Wang, M.; Mao, X. B.; Jiang, Y. X.;Wang, C.; Yang,Y. L. Acta Phys. -Chim. Sin. 2010, 26, 2037. [郭元元, 汪明,毛晓波, 蒋月秀, 王琛, 杨延莲. 物理化学学报, 2010, 26,2037.] doi: 10.3866/PKU.WHXB20100734
(4) Santos, A.; Balderrama, V. S.; Alba, M.; Formentin, P.; Ferre-Borrull, J.; Pallarès, J.; Marsal, L. F. Adv. Mater. 2012, 24, 1050.doi: 10.1002/adma.v24.8
(5) Chen,W.; Jin, B.; Hu, Y. L.; Lu, Y.; Xia, X. H. Small 2012, 7,1001.
(6) Ding, J. N.; Zhu, Y.; Yuan, N. Y.; Ding, G. Q. Thin Solid Films2012, 520, 4321. doi: 10.1016/j.tsf.2012.02.030
(7) Dong, H. Q.; Pan, X.; Xie, Q.; Meng, Q. Q.; Gao, J. R.;Wang, J.G. Acta Phys. -Chim. Sin. 2012, 28, 44. [董华青, 潘西,谢琴, 孟强强, 高建荣, 王建国. 物理化学学报, 2012, 28,44.] doi: 10.3866/PKU.WHXB20122844
(8) Li, H. H.; Chen, R. F.; Ma, C.; Zhang, S. L.; An, Z. F.; Huang,W. Acta Phys. -Chim. Sin. 2011, 27, 1017. [李欢欢, 陈润锋,马琮, 张胜兰, 安众福, 黄维. 物理化学学报, 2011, 27,1017.] doi: 10.3866/PKU.WHXB20110514
(9) Wang, D. A.; Yu, B.;Wang, C.W.; Zhou, F.; Liu,W. M. Adv. Mater. 2009, 21, 1964. doi: 10.1002/adma.v21:19
(10) Li, D. D.; Zhao, L.; Jiang, C. H.; Lu, J. G. Nano Lett. 2010, 10,2766. doi: 10.1021/nl1004493
(11) Lin, J.; Chen, J. F.; Chen, X. F. Electrochem. Commun. 2010,12, 1062. doi: 10.1016/j.elecom.2010.05.027
(12) Lee, K.; Kim, D.; Roy, P.; Paramasivam, I.; Birajdar, B. I.;Spiecker, E.; Schmuki, P. J. Am. Chem. Soc. 2010, 132, 1478.doi: 10.1021/ja910045x
(13) Xu, X. J.; Fang, X. S.; Zhai, T. Y.; Zeng, H. B.; Liu, B. D.; Hu,X. Y.; Bando, Y.; Golberg, D. Small 2011, 7, 445. doi: 10.1002/smll.201001849
(14) Lee,W.; Ji, R.; Gösele, U.; Pippel, E.; Nielsch, K. Nat. Mater.2006, 5, 741. doi: 10.1038/nmat1717
(15) Lee,W.; Schwirn, K.; Steinhart, M.; Pippel, E.; Scholz, R.;Gösele, U. Nat. Nanotechnol. 2008, 3, 234. doi: 10.1038/nnano.2008.54
(16) Ye, Q. M.; Song, Y.; Liu, P.; Hu, J. J. Prog. Chem. 2011, 23,2617. [叶秋梅, 宋晔, 刘鹏, 胡隽隽. 化学进展, 2011, 23,2617.]
(17) Li, S. Q.; Yin, J. B.; Zhang, G. M. Sci. China Chem. 2010, 53,1068. [李仕琦, 尹建波, 张耿民. 中国科学: 化学, 2010, 53,1068.] doi: 10.1007/s11426-010-0155-3
(18) Lin, J.; Liu, K.; Chen, X. F. Small 2011, 7, 1784. doi: 10.1002/smll.v7.13
(19) Li, Y.; Ling, Z. Y.; Hu, X.; Liu, Y. S.; Chang, Y. J. Mater. Chem.2011, 21, 9661. doi: 10.1039/c1jm10781j
(20) Li, Y.; Ling, Z. Y.; Hu, X.; Liu, Y. S.; Chang, Y. Chem. Commun. 2011, 47, 2173. doi: 10.1039/c0cc04907g
(21) Bolger, C. T.; Fois, G.; Petkov, N.; Sassiat, N.; Burke, M.;Quinn, A. J.; Cross, G. L.W.; Holmes, J. D. Nanotechnology2012, 23, 175602. doi: 10.1088/0957-4484/23/17/175602
(22) Sulka, G. D.; Hnida, K. Nanotechnology 2012, 23, 075303.doi: 10.1088/0957-4484/23/7/075303
(23) Cui, J.W.;Wu, Y. C.;Wang, Y.; Zheng, H. M.; Xu, G. Q.;Zhang, X. Y. Appl. Surf. Sci. 2012, 258, 5305. doi: 10.1016/j.apsusc.2012.01.099
(24) Holubowitch, N.; Nagle, L. C.; Rohan, J. F. Solid State Ionics2012, 216, 110. doi: 10.1016/j.ssi.2012.03.016
(25) Romero, V.; Vega, V.; García, J.; Prida, V. M.; Hernando, B.;Benavente, J. J. Colloid Interface Sci. 2012, 376, 40. doi: 10.1016/j.jcis.2012.02.066
(26) Roy, P.; Berger, S.; Schmuki, P. Angew. Chem. Int. Edit. 2011,50, 2904. doi: 10.1002/anie.201001374
(27) Su, Z. X.; Zhou,W. Z. J. Mater. Chem. 2011, 21, 8955. doi: 10.1039/c0jm04587j
(28) Mazzarolo, A.; Curioni, M.; Vicenzo, A.; Skeldon, P.;Thompson, G. E. Electrochim. Acta 2012, 75, 288. doi: 10.1016/j.electacta.2012.04.114
(29) Regonini, D.; Satka, A.; Jaroenworaluck, A.; Allsopp, D.W. E.;Bowen, C. R.; Stevens, R. Electrochim. Acta 2012, 74, 244.doi: 10.1016/j.electacta.2012.04.076
(30) Li, Y.; Ling, Z. Y.; Hu, X.; Liu, Y. S.; Chang, Y. RSC Adv. 2012,2, 5164. doi: 10.1039/c2ra01050j
(31) Patermarakis, G.; Diakonikolaou, J. J. Solid State Electrochem.2012, doi: 10.1007/s10008-012-1683-x
(32) Zhu, X. F.; Han, H.; Song, Y.; Duan,W. Q. Acta Phys. -Chim. Sin. 2012, 28, 1291. [朱绪飞, 韩华, 宋晔, 段文强. 物理化学学报, 2012, 28, 1291.] doi: 10.3866/PKU.WHXB201204093
(33) Wang, F.;Wei, Q. S.; Zhang, Y. L.;Wu, K.; Xie, Y. C. Acta Phys. -Chim. Sin. 2004, 20, 1134. [王凡, 卫庆硕, 张玉玲,吴凯, 谢有畅. 物理化学学报, 2004, 20, 1134.] doi: 10.3866/PKU.WHXB20040915
(34) Yin, Y. X.; Jin, Z. G.; Tan, X.; Hou, F.; Zhao, L. Acta Phys. -Chim. Sin. 2008, 24, 2133. [阴育新, 靳正国, 谭欣,侯峰, 赵林. 物理化学学报, 2008, 24, 2133.] doi: 10.3866/PKU.WHXB20081133
(35) Zhu, X. F.; Liu, L.; Song, Y.; Jia, H.; Yu, H.; Xiao, X.; Yang, X.L. Monatsh. Chem. 2008, 139, 999. doi: 10.1007/s00706-008-0893-5
(36) Zhu, X. F.; Song, Y.; Liu, L.;Wang, C.; Zheng, J.; Jia, H.;Wang,X. Nanotechnology 2009, 20, 475303. doi: 10.1088/0957-4484/20/47/475303
(37) Coz, F. L.; Arurault, L.; Datas, L. Mater. Charact. 2010, 61,283. doi: 10.1016/j.matchar.2009.12.008
(38) Gonzalez-Rovira, L.; Lopez-Haro, M.; Hungria, A. B.; Amrani,E. K.; Sanchez, J. M.; Calvino, J. J.; Botana, F. J. Corrosion Sci.2010, 52, 3763. doi: 10.1016/j.corsci.2010.07.027
(39) Skeldon, P.; Thompson, G. E.; Garcia-Vergara, S. J.; Iglesias-Rubianes, L.; Blanco-Pinzon, C. E. Electrochem. Solid St. 2006,9, B47.
(40) Garcia-Vergara, S. J.; Skeldon, P.; Thompson, G. E.; Habazaki,H. Electrochim. Acta 2006, 52, 681. doi: 10.1016/j.electacta.2006.05.054
(41) Zhu, X. F.; Song, Y.; Yu, H. D; Jia, H. B.; Yang, X. L.; Xiao, Y.H.; Lu, L. D.;Wang, X. Chinese Journal of Vacuum Science and Technology 2009, 29, 90. [朱绪飞, 宋晔, 俞华栋, 贾红兵,杨修丽, 肖迎红, 陆路德, 汪信. 真空科学与技术学报, 2009,29, 90.]
(42) Schwirn, K.; Lee,W.; Hillebrand, R.; Steinhart, M.; Nielsch, K.;Gösele, U. ACS Nano 2008, 2, 302. doi: 10.1021/nn7001322
(43) Lee,W.; Scholz, R.; Gösele, U. Nano Lett. 2008, 8, 2155.doi: 10.1021/nl080280x
(44) Patermarakis, G.; Moussoutzanis, K. Electrochim. Acta 2009,54, 2434. doi: 10.1016/j.electacta.2008.11.064
(45) Zhu, X. F.; Liu, L.; Zhao, B. C. The Chinese Journal of Nonferrous Metals 2003, 13, 1031. [朱绪飞, 刘霖, 赵宝昌.中国有色金属学报, 2003, 13, 1031.] doi: 10.3321/j.issn:1004-0609.2003.04.042

[1]	Hao-Tian Teng, Wen-Tao Wang, Xiao-Feng Han, Xiang Hao, Ruizhi Yang, Jing-Hua Tian. Recent Development and Perspectives of Flexible Zinc-Air Batteries [J]. Acta Phys. -Chim. Sin., 2023, 39(1): 2107017-0.
[2]	Zheng Bo, Jing Kong, Huachao Yang, Zhouwei Zheng, Pengpeng Chen, Jianhua Yan, Kefa Cen. Ultra-Low-Temperature Supercapacitor Based on Holey Graphene and Mixed-Solvent Organic Electrolyte [J]. Acta Phys. -Chim. Sin., 2022, 38(4): 2005054-.
[3]	Xinrun Yu, Jun Ma, Chunbo Mou, Guanglei Cui. Percolation Structure Design of Organic-inorganic Composite Electrolyte with High Lithium-Ion Conductivity [J]. Acta Phys. -Chim. Sin., 2022, 38(3): 1912061-.
[4]	Zixu He, Yawei Chen, Fanyang Huang, Yulin Jie, Xinpeng Li, Ruiguo Cao, Shuhong Jiao. Fluorinated Solvents for Lithium Metal Batteries [J]. Acta Phys. -Chim. Sin., 2022, 38(11): 2205005-.
[5]	Yuanhao Shen, Qingyu Wang, Jie Liu, Cheng Zhong, Wenbin Hu. Spontaneous Reduction and Adsorption of K₃[Fe(CN)₆] on Zn Anodes in Alkaline Electrolytes: Enabling a Long-Life Zn-Ni Battery [J]. Acta Phys. -Chim. Sin., 2022, 38(11): 2204048-0.
[6]	Jujia Zhang, Jin Zhang, Haining Wang, Yan Xiang, Shanfu Lu. Advancement in Distribution and Control Strategy of Phosphoric Acid in Membrane Electrode Assembly of High-Temperature Polymer Electrolyte Membrane Fuel Cells [J]. Acta Phys. -Chim. Sin., 2021, 37(9): 2010071-.
[7]	Liliang Tian, Weiqi Zhang, Zheng Xie, Kai Peng, Qiang Ma, Qian Xu, Sivakumar Pasupathi, Huaneng Su. Enhanced Performance and Durability of High-Temperature Polymer Electrolyte Membrane Fuel Cell by Incorporating Covalent Organic Framework into Catalyst Layer [J]. Acta Phys. -Chim. Sin., 2021, 37(9): 2009049-.
[8]	Yongli Heng, Zhenyi Gu, Jinzhi Guo, Xinglong Wu. Research Progresses on Vanadium-Based Cathode Materials for Aqueous Zinc-Ion Batteries [J]. Acta Phys. -Chim. Sin., 2021, 37(3): 2005013-.
[9]	Gaolong Zhu, Chenzi Zhao, Hong Yuan, Haoxiong Nan, Bochen Zhao, Lipeng Hou, Chuangxin He, Quanbing Liu, Jiaqi Huang. Liquid Phase Therapy with Localized High-Concentration Electrolytes for Solid-State Li Metal Pouch Cells [J]. Acta Phys. -Chim. Sin., 2021, 37(2): 2005003-.
[10]	Jun Guan, Nianwu Li, Le Yu. Artificial Interphase Layers for Lithium Metal Anode [J]. Acta Phys. -Chim. Sin., 2021, 37(2): 2009011-.
[11]	Zhida Wang, Yuancheng Feng, Songtao Lu, Rui Wang, Wei Qin, Xiaohong Wu. Improvement in Performance of Three-Dimensional SnLi/Carbon Paper Anode in Lean Electrolyte with In Situ Fluorinated Protection Layer [J]. Acta Phys. -Chim. Sin., 2021, 37(2): 2008082-.
[12]	Guangbin Hua, Yanchen Fan, Qianfan Zhang. Application of Computational Simulation on the Study of Lithium Metal Anodes [J]. Acta Phys. -Chim. Sin., 2021, 37(2): 2008089-.
[13]	Chen Wu, Ying Zhou, Xiaolong Zhu, Minzhi Zhan, Hanxi Yang, Jiangfeng Qian. Research Progress on High Concentration Electrolytes for Li Metal Batteries [J]. Acta Phys. -Chim. Sin., 2021, 37(2): 2008044-.
[14]	Yi Yang, Chong Yan, Jiaqi Huang. Research Progress of Solid Electrolyte Interphase in Lithium Batteries [J]. Acta Phys. -Chim. Sin., 2021, 37(11): 2010076-.
[15]	Han Wang, Hanwen An, Hongmei Shan, Lei Zhao, Jiajun Wang. Research Progress on Interfaces of All-Solid-State Batteries [J]. Acta Phys. -Chim. Sin., 2021, 37(11): 2007070-.

Influence of Reducer on the Nanopore Structure of Porous Anodic Alumina

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0